Solvolytic Studies on Methylnorbornyl Systems: Investigations on the Synthesis of 2-Exo-methyl-6-norbomylideneacetic Acid
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Abstract3-Nortricyclyl bromide (11) was transformed in four steps to norbornan-3,6-dione (10). Methyl 4-hydroxy-2-butynoate (19) was prepared from propargyl alcohol and its alkylation reactions with 3-methylcyclopentanone investigated. Methyl 4,4,5-triethoxycarbonylpentanoate (22) was obtained by the sequential alkylation of diethyl malonate with ethyl bromoacetate and methyl acrylate, and its base catalysed cyclization studied. Cyclopentadiene was converted to 2-exo-methylnorbornan-6-one (17) in eleven steps.
2007 ◽
Vol 72
(11)
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pp. 1579-1590
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2007 ◽
Vol 30
(1)
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pp. 200-204
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Keyword(s):
2019 ◽
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