scholarly journals Notizen: Photoredox Reaction of [Hg(cyclam)]2+[Co(CO)4]⁻ Induced by Outer Sphere Charge Transfer Excitation

1993 ◽  
Vol 48 (3) ◽  
pp. 397-398 ◽  
Author(s):  
Horst Kunkely ◽  
Arnd Vogler

The ion pair [Hg(cyclam)]2+[Co(CO)4]- displays a Co(–I) to Hg(II) metal-to-metal charge transfer (MMCT) band at 288 nm. Upon MMCT excitation the ion pair undergoes a photoconversion to [HgCO2(CO)8].

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