ChemInform Abstract: Optical Outer-sphere Ligand to Metal Charge Transfer in the Ion Pair (Ru(NH3)6)3+(Rh(CN)6)3-.

ChemInform ◽  
1988 ◽  
Vol 19 (25) ◽  
Author(s):  
A. VOGLER ◽  
H. KUNKELY
1993 ◽  
Vol 48 (3) ◽  
pp. 397-398 ◽  
Author(s):  
Horst Kunkely ◽  
Arnd Vogler

The ion pair [Hg(cyclam)]2+[Co(CO)4]- displays a Co(–I) to Hg(II) metal-to-metal charge transfer (MMCT) band at 288 nm. Upon MMCT excitation the ion pair undergoes a photoconversion to [HgCO2(CO)8].


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