Morpholine Amide Solvent: A New Inert

2009 ◽  
pp. 164-164-7
Author(s):  
Alan J. Stern ◽  
David C. Ferguson
Keyword(s):  
Amide Solvent

Complexation in the polyacrylonitrile-amide solvent-PtCl4 system

2009 ◽  
Vol 51 (8) ◽  
pp. 864-869 ◽  
Author(s):  
G. N. Bondarenko ◽  
M. N. Efimov ◽  
L. M. Zemtsov ◽  
G. P. Karpacheva
Keyword(s):  
Amide Solvent

Catalytic Activation of Molecular Hydrogen by Ruthenium Chloride Complexes in N,N-Dimethylacetamide Solution

1974 ◽  
Vol 52 (2) ◽  
pp. 348-357 ◽  
Author(s):  
Benjamin C. Hui ◽  
Brian R. James
Keyword(s):  
Aqueous System ◽  
Water Production ◽  
Chloride Complexes ◽  
Catalytic Activation ◽  
Aqueous Acid ◽  
System A ◽  
Aqueous Solvent ◽  
Lower Activation ◽  
Amide Solvent ◽  
Detailed Interpretation

N, N-Dimethylacetamide solutions of "RuCl3•3H2O", which is a mixture of Ru (IV) and Ru(III), react with hydrogen under mild conditions in stepwise stoichiometric processes to give finally univalent species [Formula: see text]. Reactions 1 and 2 involve heterolytic activation of H2 by a Ru III catalyst and likely proceed via a RuIIIH intermediate; the same catalyst catalyzes the hydrogenolysis of oxygen to water. Reaction 3 involves a RuIIH intermediate. Kinetic parameters are presented for processes 1–3 and the catalytic water production, and are compared with data for some systems that have been studied previously in aqueous acid chloride solutions. Reactions 1 and 2 occur much more readily in the non-aqueous solvent due to a lower activation energy, while reaction 3 occurs only in the non-aqueous system. A detailed interpretation of the data is limited by the uncertain nature of species present in the amide solvent.

Debundling of Single-Walled Nanotubes by Dilution:  Observation of Large Populations of Individual Nanotubes in Amide Solvent Dispersions

2006 ◽  
Vol 110 (32) ◽  
pp. 15708-15718 ◽  
Author(s):  
Silvia Giordani ◽  
Shane D. Bergin ◽  
Valeria Nicolosi ◽  
Sergei Lebedkin ◽  
Manfred M. Kappes ◽  
...  
Keyword(s):  
Single Walled Nanotubes ◽  
Large Populations ◽  
Amide Solvent

15NH/D-SOLEXSY experiment for accurate measurement of amide solvent exchange rates: application to denatured drkN SH3

2010 ◽  
Vol 46 (3) ◽  
pp. 227-244 ◽  
Author(s):  
Veniamin Chevelkov ◽  
Yi Xue ◽  
D. Krishna Rao ◽  
Julie D. Forman-Kay ◽  
Nikolai R. Skrynnikov
Keyword(s):  
Exchange Rates ◽  
Solvent Exchange ◽  
Amide Solvent ◽  
Amide Solvent Exchange

Morpholine Amide Solvent: A New Inert

2009 ◽  
Vol 6 (1) ◽  
pp. 101652 ◽  
Author(s):  
Alan J. Stern ◽  
David C. Ferguson ◽  
Arlean Rohde ◽  
Craig A. Martin ◽  
Gerald E. Otis ◽  
...  
Keyword(s):  
Amide Solvent

Solubility of benzimidazole-containing polyamides in an amide solvent-organic amine system

1982 ◽  
Vol 13 (6) ◽  
pp. 388-390
Author(s):  
N. M. Aref'ev ◽  
Z. Yu. Chereiskii ◽  
S. D. Vogman
Keyword(s):  
Organic Amine ◽  
Amine System ◽  
Amide Solvent
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