MIXED-LIGAND FLUOROOXALATE COMPLEX COMPOUNDS OF INDIUM(III) M2[InF3(C2O4)H2O] (M = K, Rb): SYNTHESIS AND CRYSTAL STRUCTURE

2017 ◽  
Keyword(s):  
Crystal Structure ◽  
Complex Compounds ◽  
Mixed Ligand ◽  
Synthesis And Crystal Structure

Mixed-Ligand Cobalt(II) and Nickel(II) Complexes with N,N,-Diethylpyridine-3-carboxamide: Synthesis and Crystal Structure

2020 ◽  
Vol 65 (8) ◽  
pp. 1160-1165
Author(s):  
T. G. Cherkasova ◽  
N. V. Pervukhina ◽  
N. V. Kuratieva ◽  
E. V. Cherkasova ◽  
I. V. Isakova ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Mixed Ligand ◽  
Synthesis And Crystal Structure

Synthesis and crystal structure of complex compounds of oxyhalogenide Mo(V) and oxythiohalogenide Mo(VI) with triphenylphosphine oxide

1988 ◽  
Vol 29 (1) ◽  
pp. 79-89
Author(s):  
G. V. Romanenko ◽  
N. V. Podberezskaya ◽  
V. P. Fedin ◽  
O. A. Geras'ko ◽  
V. E. Fedorov ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Triphenylphosphine Oxide ◽  
Complex Compounds ◽  
Synthesis And Crystal Structure

Crystal Chemistry of Uranyl Halides Containing Mixed (UO2)(XmOn)5 Bipyramids (X = Cl, Br): Synthesis and Crystal Structure of Cs2(UO2)(NO3)Cl3

2011 ◽  
Vol 66 (2) ◽  
pp. 142-s147 ◽  
Author(s):  
Evgeny V. Nazarchuk ◽  
Oleg I. Siidra ◽  
Sergey V. Krivovichev
Keyword(s):  
Crystal Structure ◽  
Chemical Composition ◽  
Single Crystals ◽  
Uranyl Nitrate ◽  
Three Dimensional ◽  
Direct Methods ◽  
Mixed Ligand ◽  
Chloride Complexes ◽  
Synthesis And Crystal Structure ◽  
Cl Atoms

Single crystals of Cs2(UO2)(NO3)Cl3 were prepared by a hydrothermal method at 205 °C. The crystal structure has been solved by Direct Methods: monoclinic, P21/n, a = 10.3748(13), b = 9.4683(13), c = 12.5535(16) Å, β = 110.280(2)◦, V = 1156.7(3) Å3, R1 = 0.029. In the structure, strongly bonded linear uranyl cations UO22+ are equatorially coordinated by two O and three Cl atoms to form (UO2)Cl3O2 pentagonal bipyramids. Each bipyramid shares its O-O edge with an adjacent (NO3)− anion to form finite clusters with the chemical composition [(UO2)(NO3)Cl3]2−. The Cs+ cations provide three-dimensional connectivity of the structure by forming Cs-O and Cs-Cl contacts to the uranyl nitrate chloride complexes. Related structures of mixed-ligand uranyl halides are compared.

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