Effect of cations on polyaniline morphology

2013 ◽  
Vol 67 (8) ◽  
Author(s):  
David Pahovnik ◽  
Ema Žagar ◽  
Jiří Vohlídal ◽  
Majda Žigon
Keyword(s):  
Ionic Liquids ◽  
Organic Electrolyte ◽  
Organic Electrolytes ◽  
Electrolyte Additives ◽  
Chemical Polymerization ◽  
Polyaniline Nanoparticles ◽  
Spectroscopic Characteristics ◽  
Ammonium Peroxodisulfate ◽  
Soft Templates ◽  
Inorganic And Organic

AbstractNanostructured polyanilines of different morphologies were prepared by chemical polymerization of aniline with ammonium peroxodisulfate in aqueous HCl using various inorganic and organic chlorides as additives with the aim to determine the effect of cations of the added electrolyte on the morphology, spectroscopic characteristics, and conductivity of formed polyanilines. Chlorides of basic metals: NaCl and CaCl2 did not show any significant effect while AlCl3 and organic electrolytes were found to influence the morphology of polyanilines. The effect of organic-electrolyte additives, which actually are ionic liquids, is explained by the organization of their molecules to micellar structures that act as soft templates for emerging polyaniline nanoparticles. The effect of AlCl3 is ascribed to the transformation of its molecules to [AlCl4]− anions.

A large-scale study of ionic liquids employed in chemistry and energy research to reveal cytotoxicity mechanisms and to develop safe design guide

2021 ◽  
Author(s):  
Lilya U. Dzhemileva ◽  
Vladimir Anatolievich D'yakonov ◽  
Marina M. Seitkalieva ◽  
Natalia Kulikovskaya ◽  
Ksenia S. Egorova ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Life Cycle ◽  
Large Scale ◽  
Energy Research ◽  
Organic Electrolytes ◽  
Large Scale Study ◽  
Design Guide ◽  
Scientific Potential

Device-level applications of organic electrolytes unavoidably imply extensive contacts with the environment. Despite their excellent scientific potential, ionic liquids (ILs) cannot be approved for practical usage until their life cycle...

Interaction of aqueous suspensions of single-walled oxidized carbon nanotubes with inorganic and organic electrolytes

2021 ◽  
pp. 117948
Author(s):  
Anna N. Laguta ◽  
Nikolay O. Mchedlov-Petrossyan ◽  
Sergey I. Bogatyrenko ◽  
Sergiy M. Kovalenko ◽  
Natalya D. Bunyatyan ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Organic Electrolytes ◽  
Aqueous Suspensions ◽  
Oxidized Carbon ◽  
Oxidized Carbon Nanotubes ◽  
Inorganic And Organic

ChemInform Abstract: Physical Chemistry of Ionic Liquids: Inorganic and Organic as Well as Protic and Aprotic

ChemInform ◽  
2013 ◽  
Vol 44 (3) ◽  
pp. no-no
Author(s):  
C. A. Angell ◽  
W. Xu ◽  
M. Yoshizawa-Fujita ◽  
A. Hayashi ◽  
J.-P. Belieres ◽  
...  
Keyword(s):  
Physical Chemistry ◽  
Ionic Liquids ◽  
Organic As ◽  
Inorganic And Organic

Physical Chemistry of Ionic Liquids: Inorganic and Organic as Well as Protic and Aprotic

2011 ◽  
pp. 5-31 ◽  
Author(s):  
C. A. Angell ◽  
W. Xu ◽  
M. Yoshizawa-Fujita ◽  
A. Hayashi ◽  
J.-P. Belieres ◽  
...  
Keyword(s):  
Physical Chemistry ◽  
Ionic Liquids ◽  
Organic As ◽  
Inorganic And Organic

The interaction of the colloidal species in hydrosols of nanodiamond with inorganic and organic electrolytes

2019 ◽  
Vol 283 ◽  
pp. 849-859 ◽  
Author(s):  
Nikolay O. Mchedlov-Petrossyan ◽  
Nika N. Kriklya ◽  
Alexander P. Kryshtal ◽  
Alexander A. Ishchenko ◽  
Maria L. Malysheva ◽  
...  
Keyword(s):  
Organic Electrolytes ◽  
Colloidal Species ◽  
Inorganic And Organic

Cycling of β-LiAl in organic electrolytes — effect of electrode contaminations and electrolyte additives

1985 ◽  
Vol 14 (1-3) ◽  
pp. 193-200 ◽  
Author(s):  
J.O. Besenhard ◽  
H.P. Fritz ◽  
E. Wudy ◽  
K. Dietz ◽  
H. Meyer
Keyword(s):  
Organic Electrolytes ◽  
Electrolyte Additives

Unusual effects of solvent polarity on capacitance for organic electrolytes in a nanoporous electrode

Nanoscale ◽  
2014 ◽  
Vol 6 (10) ◽  
pp. 5545-5550 ◽  
Author(s):  
De-en Jiang ◽  
Jianzhong Wu
Keyword(s):  
Density Functional Theory ◽  
Dipole Moment ◽  
Density Functional ◽  
Solvent Polarity ◽  
Density Functional Theory Calculations ◽  
Organic Electrolyte ◽  
Functional Theory ◽  
Organic Electrolytes

Classical density functional theory calculations suggest that there is an optimal dipole moment for the solvent in an organic electrolyte supercapacitor.

Corrigendum to “The interaction of the colloidal species in hydrosols of nanodiamond with inorganic and organic electrolytes” [J. Mol. Liq. 283 (2019) 849–859]

2019 ◽  
Vol 295 ◽  
pp. 111654
Author(s):  
Nikolay O. Mchedlov-Petrossyan ◽  
Nika N. Kriklya ◽  
Alexander P. Kryshtal ◽  
Alexander A. Ishchenko ◽  
Maria L. Malysheva ◽  
...  
Keyword(s):  
Organic Electrolytes ◽  
Colloidal Species ◽  
Inorganic And Organic
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