1,2-cis-α-Glucoside Formation from a 2-Benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl Acetate Derivative by an Activating System That Used a Combination of Ytterbium(Ill) Triflate and a Catalytic Boron Trifluoride Diethyl Etherate Complex

Heterocycles ◽  
2017 ◽  
Vol 94 (11) ◽  
pp. 2031 ◽  
Author(s):  
Takashi Yamanoi ◽  
Yoshiki Oda ◽  
Kento Fujita ◽  
Akihiko Koizumi
2014 ◽  
Vol 937 ◽  
pp. 17-22 ◽  
Author(s):  
Sheng Tao Wang ◽  
Bao Yang Lu ◽  
Jing Kun Xu ◽  
Wei Qiang Zhou

Novel poly (selenophene-co-3-methylthiophene) was successfully achieved by directly electrochemical oxidation of the monomer mixtures of selenophene and 3-methylthiophene (3MeT) in boron trifluoride diethyl etherate. The effect of monomer concentration ratios on the copolymerization were investigated by cyclic voltammetry. The structures of as-prepared copolymers were characterized by UV-vis and infrared spectroscopy. The conductivity and thermoelectric measurements revealed the incorporation of 3MeT into the polyselenophene (PSe) chain improved significantly the conductivity and thermoelectric property of PSe.


Proceedings ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 36
Author(s):  
Raquel C. R. Gonçalves ◽  
Mariana B. Nogueira ◽  
Susana P. G. Costa ◽  
M. Manuela M. Raposo

4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) derivatives 1 and 2 were obtained with 16% and 33% yield by a two-step reaction: condensation of a pyrrole with the corresponding aldehyde followed by oxidation with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in the presence of boron trifluoride diethyl etherate (BF3OEt2). The two compounds were characterized by the usual spectroscopic techniques and a detailed photophysical study was undertaken. The compounds exhibited intense absorption bands at 502 nm and 497 nm, respectively. Emission studies of the compounds 1 and 2 showed emission bands with maximum wavelength at 518 nm and 519 nm, respectively.


2005 ◽  
Vol 41 (8) ◽  
pp. 1738-1746 ◽  
Author(s):  
Liang Shen ◽  
Jingkun Xu ◽  
Zhenhong Wei ◽  
Qiang Xiao ◽  
Shouzhi Pu

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