scholarly journals Supplementary material to "Experimental determination of Henry's law constants of difluoromethane (HFC-32) and the salting-out effects in aqueous salt solutions relevant to seawater"

2017 ◽  
Author(s):  
Shuzo Kutsuna
Keyword(s):  
Experimental Determination ◽  
Henry's Law ◽  
Salt Solutions ◽  
Salting Out ◽  
Henry’S Law ◽  
Aqueous Salt Solutions ◽  
Henry’S Law Constants ◽  
Supplementary Material ◽  
Henry's Law Constants

scholarly journals Experimental determination of Henry's law constants of difluoromethane (HFC-32) and the salting-out effects in aqueous salt solutions relevant to seawater

2017 ◽  
Vol 17 (12) ◽  
pp. 7495-7507
Author(s):  
Shuzo Kutsuna
Keyword(s):  
Henry's Law ◽  
Gas Stripping ◽  
Atmospheric Gases ◽  
Salt Solutions ◽  
Salting Out ◽  
Henry’S Law ◽  
Aqueous Salt Solutions ◽  
Water Equilibrium ◽  
Hoff Equation

Abstract. Gas-to-water equilibrium coefficients, KeqS (in M atm−1), of difluoromethane (CH2F2), a hydrofluorocarbon refrigerant (HFC-32), in aqueous salt solutions relevant to seawater were determined over a temperature (T) range from 276 to 313 K and a salinity (S) range up to 51 ‰ by means of an inert-gas stripping method. From the van't Hoff equation, the KeqS value in water, which corresponds to the Henry's law constant (KH), at 298 K was determined to be 0.065 M atm−1. The salinity dependence of KeqS (the salting-out effect), ln(KH∕KeqS), did not obey the Sechenov equation but was proportional to S0. 5. Overall, the KeqS(T) value was expressed by ln(KeqS(T))  =  −49.71 + (77.70 − 0.134  ×  S0. 5)  ×  (100∕T) + 19.14  ×  ln(T∕100). By using this equation in a lower-tropospheric semi-hemisphere (30–90 °S) of the Advanced Global Atmospheric Gases Experiment (AGAGE) 12-box model, we estimated that 1 to 4 % of the atmospheric burden of CH2F2 resided in the ocean mixed layer and that this percentage was at least 4 % in the winter; dissolution of CH2F2 in the ocean may partially influence estimates of CH2F2 emissions from long-term observational data of atmospheric CH2F2 concentrations.

scholarly journals Experimental determination of Henry's law constants of difluoromethane (HFC-32) and the salting-out effects in aqueous salt solutions relevant to seawater

2017 ◽  
Author(s):  
Shuzo Kutsuna
Keyword(s):  
Henry's Law ◽  
Gas Stripping ◽  
Atmospheric Gases ◽  
Salt Solutions ◽  
Salting Out ◽  
Henry’S Law ◽  
Aqueous Salt Solutions ◽  
Water Equilibrium ◽  
Hoff Equation

Abstract. Gas-to-water equilibrium coefficients, KeqS (in M atm−1) of difluoromethane (CH2F2), a hydrofluorocarbon refrigerant (HFC-32), in aqueous salt solutions relevant to seawater were determined over a temperature (T) range from 276 to 313 K and a salinity (S) range up to 51 ‰ by means of an inert-gas stripping method. From the van't Hoff equation, the KeqS value in water, which corresponds to the Henry's law constant (KH), at 298 K was determined to be 0.064 M atm−1. The salinity dependence of KeqS (the salting-out effect), ln(KH/KeqS), did not obey the Sechenov equation but was represented by an equation involving S and S0.5. Overall, the KeqS(T) value was expressed by ln(KeqS(T)) = −49.7122 + 77.7018 × (100/T) + 19.1379 × ln(T/100) + [−0.2261 + 0.5176 × (T/100)] × S0.5 + [0.0362 − 0.1046 × (T/100)] × S. By using this equation in a lower tropospheric semi-hemisphere (30° S–90° S) of the Advanced Global Atmospheric Gases Experiment (AGAGE) 12-box model, we estimated that 1 to 5 % of the atmospheric burden of CH2F2 resided in the ocean mixed layer and that this percentage was at least 5 % in the winter; dissolution of CH2F2 in the ocean may partially influence estimates of CH2F2 emissions from long-term observational data of atmospheric CH2F2 concentrations.

A Laboratory Method for the Determination of Henry's Law Constants of Volatile Organic Chemicals

1995 ◽  
Vol 72 (1) ◽  
pp. 93 ◽  
Author(s):  
Keith C. Hansen ◽  
Zhou Zhou ◽  
Carl L. Yaws ◽  
Tejraj M. Aminabhavi
Keyword(s):  
Laboratory Method ◽  
Organic Chemicals ◽  
Henry's Law ◽  
Henry’S Law ◽  
Volatile Organic ◽  
Volatile Organic Chemicals ◽  
Henry’S Law Constants ◽  
Henry's Law Constants

Henry's law constants for polychlorinated biphenyls: experimental determination and structure-property relationships

1990 ◽  
Vol 24 (11) ◽  
pp. 1751-1754 ◽  
Author(s):  
Siegfried Brunner ◽  
Eduard Hornung ◽  
Helmut Santl ◽  
Egmont Wolff ◽  
Otto G. Piringer ◽  
...  
Keyword(s):  
Polychlorinated Biphenyls ◽  
Experimental Determination ◽  
Henry's Law ◽  
Structure Property ◽  
Henry’S Law ◽  
Structure Property Relationships ◽  
Henry’S Law Constants ◽  
Henry's Law Constants

Determination of Henry's law constants for low volatile mixed halogenated anisoles using solid-phase microextraction

2007 ◽  
Vol 589 (1) ◽  
pp. 133-136 ◽  
Author(s):  
Alfredo Diaz ◽  
Francesc Ventura ◽  
Ma Teresa Galceran
Keyword(s):  
Solid Phase Microextraction ◽  
Solid Phase ◽  
Henry's Law ◽  
Henry’S Law ◽  
Henry’S Law Constants ◽  
Henry's Law Constants

Determination of the Henry's law constants of low-volatility compounds via the measured air-phase transfer coefficients

2017 ◽  
Vol 120 ◽  
pp. 238-244 ◽  
Author(s):  
Huan-Ping Chao ◽  
Jiunn-Fwu Lee ◽  
Cary T. Chiou
Keyword(s):  
Phase Transfer ◽  
Henry's Law ◽  
Transfer Coefficients ◽  
Henry’S Law ◽  
Henry’S Law Constants ◽  
Henry's Law Constants
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