titanium alkylidene
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1,2-CH Bond Activation of Pyridine across a Transient Titanium Alkylidene Radical and Re-Formation of the Ti═CHtBu Moiety

2017 ◽  
Vol 37 (2) ◽  
pp. 165-167 ◽  
Author(s):  
Takashi Kurogi ◽  
Matthias E. Miehlich ◽  
Dominik Halter ◽  
Daniel J. Mindiola
Keyword(s):  
Bond Activation ◽  
Titanium Alkylidene ◽  
Ch Bond Activation

Intermetallic Cooperation in C–H Activation Involving Transient Titanium-Alkylidene Species: A Synthetic and Mechanistic Study

2017 ◽  
Vol 36 (16) ◽  
pp. 3076-3083 ◽  
Author(s):  
Jorge J. Carbó ◽  
Diego García-López ◽  
María Gómez-Pantoja ◽  
Juan I. González-Pérez ◽  
Avelino Martín ◽  
...  
Keyword(s):  
Mechanistic Study ◽  
Titanium Alkylidene

N–N bond cleavage in diazoalkanes with a titanium alkylidene

Polyhedron ◽  
2014 ◽  
Vol 84 ◽  
pp. 177-181 ◽  
Author(s):  
Jun-ichi Ito ◽  
Marco G. Crestani ◽  
Brad C. Bailey ◽  
Xinfeng Gao ◽  
Daniel J. Mindiola
Keyword(s):  
Bond Cleavage ◽  
Titanium Alkylidene

Lewis Acid Promoted Titanium Alkylidene Formation: Off-Cycle Intermediates Relevant to Olefin Trimerization Catalysis

2014 ◽  
Vol 136 (30) ◽  
pp. 10790-10800 ◽  
Author(s):  
Aaron Sattler ◽  
David G. VanderVelde ◽  
Jay A. Labinger ◽  
John E. Bercaw
Keyword(s):  
Lewis Acid ◽  
Titanium Alkylidene

Synthesis, Bonding and Reactivity of a Terminal Titanium Alkylidene Hydrazido Compound

2013 ◽  
Vol 19 (13) ◽  
pp. 4198-4216 ◽  
Author(s):  
Pei Jen Tiong ◽  
Laura R. Groom ◽  
Eric Clot ◽  
Philip Mountford
Keyword(s):  
Titanium Alkylidene

1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the C–F bond activation pathway and rotation of the titanium alkylidene moiety

2011 ◽  
Vol 696 (25) ◽  
pp. 4138-4146 ◽  
Author(s):  
José G. Andino ◽  
Hongjun Fan ◽  
Alison R. Fout ◽  
Brad C. Bailey ◽  
Mu-Hyun Baik ◽  
...  
Keyword(s):  
Bond Activation ◽  
Activation Pathway ◽  
Titanium Alkylidene

ChemInform Abstract: Olefinic Ester and Diene Ring-Closing Metathesis Using a Reduced Titanium Alkylidene.

ChemInform ◽  
2008 ◽  
Vol 39 (12) ◽  
Author(s):  
Karthik Iyer ◽  
Jon D. Rainier
Keyword(s):  
Ring Closing Metathesis ◽  
Titanium Alkylidene
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