Palladium-Catalyzed Divergent Reactions of α-Diazocarbonyl Compounds with Allylic Esters: Construction of Quaternary Carbon Centers

2011 ◽  
Vol 124 (6) ◽  
pp. 1399-1403 ◽  
Author(s):  
Zi-Sheng Chen ◽  
Xin-Hua Duan ◽  
Ping-Xin Zhou ◽  
Shaukat Ali ◽  
Jian-Yi Luo ◽  
...  
Keyword(s):  
Quaternary Carbon ◽  
Carbon Centers ◽  
Palladium Catalyzed ◽  
Allylic Esters

Palladium-Catalyzed Divergent Reactions of α-Diazocarbonyl Compounds with Allylic Esters: Construction of Quaternary Carbon Centers

2011 ◽  
Vol 51 (6) ◽  
pp. 1370-1374 ◽  
Author(s):  
Zi-Sheng Chen ◽  
Xin-Hua Duan ◽  
Ping-Xin Zhou ◽  
Shaukat Ali ◽  
Jian-Yi Luo ◽  
...  
Keyword(s):  
Quaternary Carbon ◽  
Carbon Centers ◽  
Palladium Catalyzed ◽  
Allylic Esters

ChemInform Abstract: Palladium-Catalyzed Divergent Reactions of α-Diazocarbonyl Compounds with Allylic Esters: Construction of Quaternary Carbon Centers.

ChemInform ◽  
2012 ◽  
Vol 43 (25) ◽  
pp. no-no
Author(s):  
Zi-Sheng Chen ◽  
Xin-Hua Duan ◽  
Ping-Xin Zhou ◽  
Shaukat Ali ◽  
Jian-Yi Luo ◽  
...  
Keyword(s):  
Quaternary Carbon ◽  
Carbon Centers ◽  
Palladium Catalyzed ◽  
Allylic Esters

Construction of Chiral Quaternary Carbon Centers via Palladium-Catalyzed Asymmetric Deconjugative Allylation

Heterocycles ◽  
2008 ◽  
Vol 76 (2) ◽  
pp. 1485 ◽  
Author(s):  
Yoshihiro Sato ◽  
Hiroki Yamamoto ◽  
Yoshihiro Oonishi
Keyword(s):  
Quaternary Carbon ◽  
Carbon Centers ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Direct Arylation of C-H Bond to Construct Quaternary Carbon Centers: The Synthesis of Diarylfluorene.

ChemInform ◽  
2013 ◽  
Vol 44 (47) ◽  
pp. no-no
Author(s):  
Xiao Cao ◽  
Weidong Yang ◽  
Chao Liu ◽  
Fuliang Wei ◽  
Kun Wu ◽  
...  
Keyword(s):  
Quaternary Carbon ◽  
Direct Arylation ◽  
Carbon Centers ◽  
Palladium Catalyzed

Palladium-catalyzed trisallylation of benzoxazoles and 2-aryl-1,3,4-oxadiazoles with alkyne

2019 ◽  
Vol 55 (5) ◽  
pp. 624-627 ◽  
Author(s):  
Jun Zheng ◽  
Fereshteh Hosseini-Eshbala ◽  
Ya-Xi Dong ◽  
Bernhard Breit
Keyword(s):  
Quaternary Carbon ◽  
Atom Economy ◽  
Olefin Isomerization ◽  
Carbon Centers ◽  
Wide Range ◽  
Palladium Catalyzed

In this report, a palladium catalyzed direct trisallylation of azoles with alkyne via a novel subsequent mono C(sp2)–H allylation/olefin isomerization/y-selective double C(sp3)–H allylation process was developed. A wide range of substituted trisallylated azoles bearing all quaternary carbon centers has been synthesized efficiently and with high atom economy.

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