Catalytic Asymmetric Inverse-Electron-Demand Oxa-Diels-Alder Reaction of In Situ Generatedortho-Quinone Methides with 3-Methyl-2-Vinylindoles

2015 ◽  
Vol 127 (18) ◽  
pp. 5550-5554 ◽  
Author(s):  
Jia-Jia Zhao ◽  
Si-Bing Sun ◽  
Sai-Huan He ◽  
Qiong Wu ◽  
Feng Shi
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Quinone Methides ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes

2018 ◽  
Vol 54 (20) ◽  
pp. 2506-2509 ◽  
Author(s):  
Liang Wei ◽  
Qiao Zhu ◽  
Zhi-Min Song ◽  
Kang Liu ◽  
Chun-Jiang Wang
Keyword(s):  
Good Yield ◽  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

An unprecedented copper(i)-catalyzed asymmetric inverse electron demand Diels–Alder reaction of azoalkenes with fulvenes is reported. This methodology offers a directed entry to synthesize bicyclic tetrapyridazine derivatives in good yield with exclusive regioselectivity and excellent stereoselectivity.

An Inverse Electron Demand Azo-Diels–Alder Reaction ofo-Quinone Methides and Imino Ethers: Synthesis of Benzocondensed 1,3-Oxazines

2018 ◽  
Vol 83 (8) ◽  
pp. 4775-4785 ◽  
Author(s):  
Dmitry V. Osipov ◽  
Vitaly A. Osyanin ◽  
Guzel’ D. Khaysanova ◽  
Elvira R. Masterova ◽  
Pavel E. Krasnikov ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Quinone Methides ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand
Sign in / Sign up

Export Citation Format

Share Document