Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes

2018 ◽  
Vol 54 (20) ◽  
pp. 2506-2509 ◽  
Author(s):  
Liang Wei ◽  
Qiao Zhu ◽  
Zhi-Min Song ◽  
Kang Liu ◽  
Chun-Jiang Wang
Keyword(s):  
Good Yield ◽  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

An unprecedented copper(i)-catalyzed asymmetric inverse electron demand Diels–Alder reaction of azoalkenes with fulvenes is reported. This methodology offers a directed entry to synthesize bicyclic tetrapyridazine derivatives in good yield with exclusive regioselectivity and excellent stereoselectivity.

The catalytic asymmetric synthesis of tetrahydropyridazines via inverse electron-demand aza-Diels–Alder reaction of enol ethers with azoalkenes

2015 ◽  
Vol 51 (84) ◽  
pp. 15374-15377 ◽  
Author(s):  
Liang Wei ◽  
Chun-Jiang Wang
Keyword(s):  
Asymmetric Synthesis ◽  
Good Yield ◽  
Alder Reaction ◽  
Diels Alder ◽  
Enol Ethers ◽  
Inverse Electron Demand ◽  
Catalytic Asymmetric Synthesis ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

A highly efficient catalytic asymmetric IEDDA reaction of azoalkenes with enol ethers is reported. This methodology provides a facile entry to biologically important tetrahydropyridazines in good yield with good to excellent ee.

Catalytic Asymmetric Inverse-Electron-Demand Hetero-Diels–Alder Reaction of Dioxopyrrolidines with Hetero-Substituted Alkenes

2018 ◽  
Vol 83 (15) ◽  
pp. 8679-8687 ◽  
Author(s):  
Xinyue Hu ◽  
Yuhang zhou ◽  
Yan Lu ◽  
Sijia Zou ◽  
Lili Lin ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

Catalytic Asymmetric Inverse-Electron-Demand Diels−Alder Reaction ofN-Sulfonyl-1-Aza-1,3-Dienes

2007 ◽  
Vol 129 (6) ◽  
pp. 1480-1481 ◽  
Author(s):  
Jorge Esquivias ◽  
Ramón Gómez Arrayás ◽  
Juan C. Carretero
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

scholarly journals Catalytic Asymmetric Inverse-Electron-Demand Diels—Alder Reaction of N-Sulfonyl-1-aza-1,3-dienes.

ChemInform ◽  
2007 ◽  
Vol 38 (24) ◽  
Author(s):  
Jorge Esquivias ◽  
Ramon Gomez Arrayas ◽  
Juan C. Carretero
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand
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