scholarly journals Molecular Weight Control via Cross Metathesis in Photo‐Redox Mediated Ring‐Opening Metathesis Polymerization

2020 ◽  
Vol 132 (23) ◽  
pp. 9159-9164
Author(s):  
Victoria K. Kensy ◽  
Rachel L. Tritt ◽  
Farihah M. Haque ◽  
Laura M. Murphy ◽  
Daniel B. Knorr ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ring Opening ◽  
Weight Control ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Molecular Weight Control ◽  
Cross Metathesis

scholarly journals Molecular Weight Control via Cross Metathesis in Photo‐Redox Mediated Ring‐Opening Metathesis Polymerization

2020 ◽  
Vol 59 (23) ◽  
pp. 9074-9079 ◽  
Author(s):  
Victoria K. Kensy ◽  
Rachel L. Tritt ◽  
Farihah M. Haque ◽  
Laura M. Murphy ◽  
Daniel B. Knorr ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ring Opening ◽  
Weight Control ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Molecular Weight Control ◽  
Cross Metathesis

scholarly journals Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

2019 ◽  
Vol 15 ◽  
pp. 310-332 ◽  
Author(s):  
Patrycja Żak ◽  
Cezary Pietraszuk
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Polymeric Materials ◽  
Acyclic Diene Metathesis ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Cross Metathesis ◽  
Terminal Olefins ◽  
Synthesized Materials

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.

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