An Unexpected Reaction of Arenesulfonyl Cyanides with Allylic Alcohols: Preparation of Trisubstituted Allyl Sulfones

2008 ◽  
Vol 48 (1) ◽  
pp. 172-174 ◽  
Author(s):  
Leleti Rajender Reddy ◽  
Bin Hu ◽  
Mahavir Prashad ◽  
Kapa Prasad
Keyword(s):  
Allylic Alcohols ◽  
Unexpected Reaction

An Unexpected Reaction of Arenesulfonyl Cyanides with Allylic Alcohols: Preparation of Trisubstituted Allyl Sulfones

2008 ◽  
Vol 121 (1) ◽  
pp. 178-180 ◽  
Author(s):  
Leleti Rajender Reddy ◽  
Bin Hu ◽  
Mahavir Prashad ◽  
Kapa Prasad
Keyword(s):  
Allylic Alcohols ◽  
Unexpected Reaction

ChemInform Abstract: An Unexpected Reaction of Arenesulfonyl Cyanides with Allylic Alcohols: Preparation of Trisubstituted Allyl Sulfones.

ChemInform ◽  
2009 ◽  
Vol 40 (19) ◽  
Author(s):  
Leleti Rajender Reddy ◽  
Bin Hu ◽  
Mahavir Prashad ◽  
Kapa Prasad
Keyword(s):  
Allylic Alcohols ◽  
Unexpected Reaction

Active MnO2 As a Mild Oxidizing Reagent for the Controlled Oxidation of Benzylic and Allylic Alcohols

2012 ◽  
Vol 2 (6) ◽  
pp. 48-48
Author(s):  
Y. M. Nandurkar Y. M. Nandurkar ◽  
◽  
B. B. Bahule B. B. Bahule
Keyword(s):  
Allylic Alcohols

Bimetallic Radical Redox-Relay Catalysis for the Isomerization of Epoxides to Allylic Alcohols

2019 ◽  
Author(s):  
Ke-Yin Ye ◽  
Terry McCallum ◽  
Song Lin
Keyword(s):  
Ring Opening ◽  
High Reactivity ◽  
Hydrogen Atom Transfer ◽  
Organic Radicals ◽  
Epoxide Ring ◽  
Allylic Alcohols ◽  
Epoxide Ring Opening ◽  
Bond Forming ◽  
Co Catalysts ◽  
The Rich

Organic radicals are generally short-lived intermediates with exceptionally high reactivity. Strategically, achieving synthetically useful transformations mediated by organic radicals requires both efficient initiation and selective termination events. Here, we report a new catalytic strategy, namely bimetallic radical redox-relay, in the regio- and stereoselective rearrangement of epoxides to allylic alcohols. This approach exploits the rich redox chemistry of Ti and Co complexes and merges reductive epoxide ring opening (initiation) with hydrogen atom transfer (termination). Critically, upon effecting key bond-forming and -breaking events, Ti and Co catalysts undergo proton-transfer/electron-transfer with one another to achieve turnover, thus constituting a truly synergistic dual catalytic system.<br>

Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

2020 ◽  
Vol 59 (46) ◽  
pp. 20394-20398
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Yao Ge ◽  
Weiheng Huang ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Dicarboxylic Acids ◽  
Allylic Alcohols ◽  
Selective Synthesis ◽  
Palladium Catalyzed

scholarly journals Boron-catalyzed dehydrative allylation of 1,3-diketones and β-ketone esters with 1,3-diarylallyl alcohols in water

RSC Advances ◽  
2021 ◽  
Vol 11 (28) ◽  
pp. 17025-17031
Author(s):  
Guo-Min Zhang ◽  
Hua Zhang ◽  
Bei Wang ◽  
Ji-Yu Wang
Keyword(s):  
Allylic Alcohols

Allylic alcohols can directly dehydrated in water by B(C6F5)3, without any base additives.

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