Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents

2012 ◽  
Vol 51 (8) ◽  
pp. 1922-1925 ◽  
Author(s):  
Martín Fañanás-Mastral ◽  
Manuel Pérez ◽  
Pieter H. Bos ◽  
Alena Rudolph ◽  
Syuzanna R. Harutyunyan ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Alkylation ◽  
Stereogenic Centers ◽  
Organolithium Reagents ◽  
Quaternary Stereogenic Centers

Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents

2012 ◽  
Vol 124 (8) ◽  
pp. 1958-1961 ◽  
Author(s):  
Martín Fañanás-Mastral ◽  
Manuel Pérez ◽  
Pieter H. Bos ◽  
Alena Rudolph ◽  
Syuzanna R. Harutyunyan ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Alkylation ◽  
Stereogenic Centers ◽  
Organolithium Reagents ◽  
Quaternary Stereogenic Centers

scholarly journals Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)

2018 ◽  
Vol 9 (3) ◽  
pp. 546-559 ◽  
Author(s):  
Tao Jia ◽  
Peng Cao ◽  
Jian Liao
Keyword(s):  
Transition Metal ◽  
Enantioselective Synthesis ◽  
Transfer Reactions ◽  
Stereogenic Centers ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Quaternary Stereogenic Centers ◽  
Aryl Transfer

To date, enantiomerically enriched molecules containing gem(1,1)-diaryl containing tertiary or quaternary stereogenic centers have been readily accessed by transition metal-catalyzed enantioselective or stereoconvergent aryl transfer reactions.

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