aryl transfer
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Refining boron-iodane exchange to access versatile arylation reagents

2022 ◽  
Author(s):  
Shubhendu Karandikar ◽  
David Ross Stuart
Keyword(s):  
Iodonium Salts ◽  
Aryl Transfer

Aryl(Mes)iodonium salts, which are multifaceted aryl transfer reagents, are synthesized via boron-iodane exchange. Modification to both the nucleophilic (aryl boron) and electrophilic (mesityl-λ3-iodane) reaction components result in improved yield and...

Gold-to-Boron Aryl Transfer from a T-Shaped Phosphine–Borane Gold(I) Complex

2021 ◽  
Author(s):  
Cyril A. Theulier ◽  
Yago García-Rodeja ◽  
Sonia Mallet-Ladeira ◽  
Karinne Miqueu ◽  
Ghenwa Bouhadir ◽  
...  
Keyword(s):  
Aryl Transfer

Ionic liquid-mediated benzoyl transfer-coupling in the Suzuki and Sonogashira reactions and aryl transfer-coupling by decarbonylative Heck reaction, using N-Benzoyl-saccharin (NBSac) as reagent

2020 ◽  
Vol 61 (24) ◽  
pp. 151987 ◽  
Author(s):  
Shruti S. Malunavar ◽  
Suraj M. Sutar ◽  
Pavankumar Prabhala ◽  
Rajesh G. Kalkhambkar ◽  
Kenneth K. Laali
Keyword(s):  
Ionic Liquid ◽  
Heck Reaction ◽  
Sonogashira Reactions ◽  
Aryl Transfer

Metal-Free Addition of Boronic Acids to Silylnitronates

Synlett ◽  
2020 ◽  
Vol 31 (09) ◽  
pp. 856-860
Author(s):  
Laurent El Kaïm ◽  
Mansour Dolé Kerim ◽  
Pakoupati Boyode ◽  
Julian Garrec
Keyword(s):  
Reaction Mechanism ◽  
Double Bond ◽  
Boronic Acids ◽  
Dft Study ◽  
Metal Free ◽  
Nitro Derivatives ◽  
Oxime Derivatives ◽  
Nitrogen Double Bond ◽  
First Time ◽  
Aryl Transfer

We report for the first time a metal-free addition of boronic acids to silylnitronates to afford oxime derivatives through aryl transfer on the carbon nitrogen double bond. A reaction mechanism has been proposed in relation with a DFT study on the key aryl transfer. This arylation process is effective for cycloalkenyl nitro derivatives leading to oximes that may be oxidatively converted into 3-arylisoxazole derivatives.

Iodine-mediated aryl transfer reaction from arylhydrazine hydrochlorides to nitriles

Tetrahedron ◽  
2019 ◽  
Vol 75 (26) ◽  
pp. 3628-3635 ◽  
Author(s):  
Zhiguo Zhang ◽  
Xiang Li ◽  
Yinghua Li ◽  
Yan Guo ◽  
Xunan Zhao ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Aryl Transfer

Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium(III) reagents

2019 ◽  
Vol 60 (18) ◽  
pp. 1281-1286 ◽  
Author(s):  
Daichi Koseki ◽  
Erika Aoto ◽  
Toshitaka Shoji ◽  
Kazuma Watanabe ◽  
Yasuko In ◽  
...  
Keyword(s):  
Aryl Transfer
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