Transition-Metal Complexes [(PMe3)2Cl2M(E)] and [(PMe3)2(CO)2M(E)] with Naked Group 14 Atoms (E=C-Sn) as Ligands; Part 2: Complexation with W(CO)5

2009 ◽  
Vol 15 (35) ◽  
pp. 8817-8824 ◽  
Author(s):  
Pattiyil Parameswaran ◽  
Gernot Frenking
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Group 14

scholarly journals Group 10–group 14 metal complexes [E–TM]IV: the role of the group 14 site as an L, X and Z-type ligand

2016 ◽  
Vol 45 (36) ◽  
pp. 14252-14264 ◽  
Author(s):  
Erik Wächtler ◽  
Robert Gericke ◽  
Erica Brendler ◽  
Birgit Gerke ◽  
Thorsten Langer ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Group 14 ◽  
Group 10

The group 14 element's ligand role in N,S-bridged transition metal complexes was shown to depend on both atoms’ substitution patterns.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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