Direct Regiospecific and Highly Enantioselective Intermolecular α-Allylic Alkylation of Aldehydes by a Combination of Transition-Metal and Chiral Amine Catalysts

2012 ◽  
Vol 18 (10) ◽  
pp. 2972-2977 ◽  
Author(s):  
Samson Afewerki ◽  
Ismail Ibrahem ◽  
Jonas Rydfjord ◽  
Palle Breistein ◽  
Armando Córdova
Keyword(s):  
Transition Metal ◽  
Allylic Alkylation ◽  
Chiral Amine ◽  
Amine Catalysts

ChemInform Abstract: Direct Regiospecific and Highly Enantioselective Intermolecular α-Allylic Alkylation of Aldehydes by a Combination of Transition-Metal and Chiral Amine Catalysts.

ChemInform ◽  
2012 ◽  
Vol 43 (29) ◽  
pp. no-no
Author(s):  
Samson Afewerki ◽  
Ismail Ibrahem ◽  
Jonas Rydfjord ◽  
Palle Breistein ◽  
Armando Cordova
Keyword(s):  
Transition Metal ◽  
Allylic Alkylation ◽  
Chiral Amine ◽  
Amine Catalysts

ChemInform Abstract: Chiral Recognition for Control of Alkene Geometry in a Transition Metal Catalyzed Allylic Alkylation.

ChemInform ◽  
2010 ◽  
Vol 31 (3) ◽  
pp. no-no
Author(s):  
Barry M. Trost ◽  
Christoph Heinemann ◽  
Xavier Ariza ◽  
Stefan Weigand
Keyword(s):  
Transition Metal ◽  
Chiral Recognition ◽  
Allylic Alkylation ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Catalytic Regioselective Benzoylation of 1,2-trans-Diols in Carbohydrates with Benzoyl Cyanide: The Axial Oxy Group Effect and the Action of Achiral and Chiral Amine Catalysts

ACS Catalysis ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 11406-11416 ◽  
Author(s):  
Tianlu Li ◽  
Tong Li ◽  
Michael Linseis ◽  
Fengshan Wang ◽  
Rainer F. Winter ◽  
...  
Keyword(s):  
Group Effect ◽  
Chiral Amine ◽  
Benzoyl Cyanide ◽  
Amine Catalysts

scholarly journals Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

2018 ◽  
Vol 20 (2) ◽  
pp. 425-430 ◽  
Author(s):  
Seema A. Ghorpade ◽  
Dinesh N. Sawant ◽  
Arwa Makki ◽  
Nagaiyan Sekar ◽  
Jörg Eppinger
Keyword(s):  
Transition Metal ◽  
Nucleophilic Substitution ◽  
Allylic Alkylation ◽  
Substitution Reactions ◽  
Allylic Amination ◽  
Metal Free ◽  
Nucleophilic Substitution Reactions ◽  
Water Based

A transition metal free, reagent free, only water based, greener protocol for the allylic alkylation, allylic amination, and O-allylation of (E)-1,3-diphenylallyl acetate is described.

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