Palladium-Catalyzed One-Pot Three- or Four-Component Coupling of Aryl Iodides, Alkynes, and Amines through CN Bond Cleavage: Efficient Synthesis of Indole Derivatives

2014 ◽  
Vol 20 (9) ◽  
pp. 2605-2612 ◽  
Author(s):  
Wei Hao ◽  
Weizhi Geng ◽  
Wen-Xiong Zhang ◽  
Zhenfeng Xi
2019 ◽  
Vol 15 ◽  
pp. 291-298 ◽  
Author(s):  
Yue Zhong ◽  
Wen-Yu Wu ◽  
Shao-Peng Yu ◽  
Tian-Yuan Fan ◽  
Hai-Tao Yu ◽  
...  

Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromobenzoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleasantly, this protocol has a wider substrate range, shorter reaction times and higher yields of products than previously reported methods.


2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Mohammad Bakherad ◽  
Farzaneh Gholipoor

An efficient synthesis of 3-benzyl-substituted 7H-thiazolo[3,2-a]pyrimine-7-ones in acetonitrile is accomplished via Pd- and Cu-catalyzed reaction of 2-mercaptopropargylpyrimidone with various aryl iodides in the presence of triethylamine as the base.


2002 ◽  
Vol 664 (1-2) ◽  
pp. 223-227 ◽  
Author(s):  
Sandra E Martı́n ◽  
Mariana Bonaterra ◽  
Roberto A Rossi

ACS Catalysis ◽  
2013 ◽  
Vol 3 (2) ◽  
pp. 178-181 ◽  
Author(s):  
Qilun Liu ◽  
Pinhong Chen ◽  
Guosheng Liu

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