scholarly journals Regioselective Syntheses of 3-Benzyl-Substituted 7H-Thiazolo[3,2-a]pyrimidine-7-ones through Palladium-Catalyzed Heteroannulation of Acetylenic Compounds

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Mohammad Bakherad ◽  
Farzaneh Gholipoor

An efficient synthesis of 3-benzyl-substituted 7H-thiazolo[3,2-a]pyrimine-7-ones in acetonitrile is accomplished via Pd- and Cu-catalyzed reaction of 2-mercaptopropargylpyrimidone with various aryl iodides in the presence of triethylamine as the base.

ACS Catalysis ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 2977-2983 ◽  
Author(s):  
Jin-Bao Peng ◽  
Fu-Peng Wu ◽  
Da Li ◽  
Hui-Qing Geng ◽  
Xinxin Qi ◽  
...  

2016 ◽  
Vol 2016 (34) ◽  
pp. 5616-5619 ◽  
Author(s):  
Hai-Yu He ◽  
Wei Wang ◽  
Xiao-Jun Yu ◽  
Jin Huang ◽  
Lei Jian ◽  
...  

2018 ◽  
Vol 360 (21) ◽  
pp. 4153-4160 ◽  
Author(s):  
Jin‐Bao Peng ◽  
Bo Chen ◽  
Xinxin Qi ◽  
Jun Ying ◽  
Xiao‐Feng Wu

2019 ◽  
Vol 15 ◽  
pp. 291-298 ◽  
Author(s):  
Yue Zhong ◽  
Wen-Yu Wu ◽  
Shao-Peng Yu ◽  
Tian-Yuan Fan ◽  
Hai-Tao Yu ◽  
...  

Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromobenzoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleasantly, this protocol has a wider substrate range, shorter reaction times and higher yields of products than previously reported methods.


2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.


Sign in / Sign up

Export Citation Format

Share Document