Brønsted Acid Catalyzed [3+2]-Cycloaddition of 2-Vinylindoles with In Situ Generated 2-Methide-2H-indoles: Highly Enantioselective Synthesis of Pyrrolo[1,2-a]indoles

2016 ◽  
Vol 22 (21) ◽  
pp. 7074-7078 ◽  
Author(s):  
Kalisankar Bera ◽  
Christoph Schneider
2015 ◽  
Vol 51 (8) ◽  
pp. 1461-1464 ◽  
Author(s):  
Satyajit Saha ◽  
Santosh Kumar Alamsetti ◽  
Christoph Schneider

Hydrogen-bonded, in situ-generated ortho-quinone methides undergo highly enantioselective Friedel–Crafts reactions with indoles and naphthols under mild reaction conditions.


2016 ◽  
Vol 52 (10) ◽  
pp. 2071-2074 ◽  
Author(s):  
Josipa Suć ◽  
Irena Dokli ◽  
Matija Gredičak

Chiral Brønsted acid catalyzed synthesis of N(acyl),S-acetals from in situ generated ketimines proceeds in high yields and enantioselectivities.


Author(s):  
Xue-Jiao Lv ◽  
Yong-Chao Ming ◽  
Hui-Chun Wu ◽  
Yankai Liu

A Brønsted acid-catalyzed cascade acyclic N,O-hemiaminal formation/oxa-Michael reaction is developed for the synthesis of cis-2,6-disubstituted tetrahydropyrans bearing an exo amide group, that is, cyclic N,O-aminals. By using TsOH, various different...


2015 ◽  
Vol 357 (4) ◽  
pp. 672-676 ◽  
Author(s):  
Christian Beceño ◽  
Pankaj Chauhan ◽  
Andreas Rembiak ◽  
Ai Wang ◽  
Dieter Enders

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