ChemInform Abstract: GROUP IV ORGANOMETALLIC CHEMISTRY. II. PREPARATION AND PROPERTIES OF DITHIACYCLOPENTANE AND DITHIACYCLOHEXANE DERIVATIVES OF SILICON, GERMANIUM, AND TIN

1976 ◽  
Vol 7 (5) ◽  
pp. no-no
Author(s):  
R. H. CRAGG ◽  
A. TAYLOR
Keyword(s):  
Organometallic Chemistry ◽  
Silicon Germanium ◽  
Group Iv ◽  
Abstract Group ◽  
Derivatives Of

Dicarbonylcycloheptatrienylmolybdenum Derivatives of Silicon, Germanium, and Tin

1975 ◽  
Vol 53 (7) ◽  
pp. 975-978 ◽  
Author(s):  
E. E. Isaacs ◽  
W. A. G. Graham
Keyword(s):  
Silicon Germanium ◽  
Mass Spectrometric ◽  
Derivatives Of

Convenient procedures are reported for the synthesis of the compounds (η-C7H7)Mo(CO)2MR3 (M = Si, R = Cl; M = Ge, R = Cl, F, Ph; M = Sn, R = Cl, Ph ). The triphenyl derivatives were accessible through the anion [(η-C7H7)Mo(CO)2]−, while the MCl3 derivatives were prepared from (η-C7H7)Mo(CO)2Cl. Infrared, n.m.r., and mass spectrometric properties are reported.

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