ChemInform Abstract: RADICAL IONS. 14. ELECTRONIC STRUCTURE OF SULFUR COMPOUNDS. 23. THIATHIONE RADICAL ANIONS- ARE (-S)2C-S GROUPS ELECTRON TRAPS.

1978 ◽  
Vol 9 (2) ◽  
Author(s):  
H. BOCK ◽  
G. BRAEHLER ◽  
A. TABATABAI ◽  
A. SEMKOW ◽  
R. GLEITER
Keyword(s):  
Electronic Structure ◽  
Sulfur Compounds ◽  
Radical Anions ◽  
Radical Ions ◽  
Electron Traps

Chemistry of radical ions: the absolute rate constant of dimerization of radical anions of 1 ,1-diphenyl ethylene

1965 ◽  
Vol 288 (1413) ◽  
pp. 212-223 ◽  
Keyword(s):  
Electron Transfer ◽  
Rate Constant ◽  
Transfer Process ◽  
Aromatic Hydrocarbons ◽  
Radical Anions ◽  
Electron Affinities ◽  
Absolute Rate ◽  
Radical Ions ◽  
Electron Transfer Process ◽  
Absolute Rate Constant

The combination of the labile radical ions, (Ph 2 C:CH 2 )7~, Na+, into dimeric dianions Na + , C - (Ph) 2 .CH 2 .CH 2 .C(Ph) - 2, Na+ was investigated by a flow and a stopflow technique. The bimolecular rate constant of combination was found to be 2 to 3 x 106 1. mole-1 s-1. The reaction was initiated by an electron transfer naphthalene^ + (P/*,2C:CH2) naphthalene+ (P/*,2C:CH^) or terphenylener + (P7fc2C:CH2) ⇔ terphenylene + (Pfe2C:CH^). The equilibrium constant of the first electron transfer process was found to be 20 and of the second about 16. These results are consistent with recent determinations of electron affinities of aromatic hydrocarbons.

Electronic structure and reactivity of X2Co2(CO)6 (X2  RC2R′, P2, As2) and RxR′ 6-xC6Co2(CO)4 radical anions

1979 ◽  
Vol 172 (4) ◽  
pp. C63-C65 ◽  
Author(s):  
R.S. Dickson ◽  
B.M. Peake ◽  
P.H. Rieger ◽  
B.H. Robinson ◽  
J. Simpson
Keyword(s):  
Electronic Structure ◽  
Radical Anions
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