Recovery and utilization of phosphorus from fruit and vegetable wastewater

Excessive discharge of phosphorus into the water bodies is the key factor to cause eutrophication. The fruit and vegetable wastewater contains large amounts of phosphorus, and it may be directly discharged into water bodies, which has a great burden on the municipal sewage pipe network. Therefore, coagulation was used to remove phosphorus, recovered the phosphorus from the wastewater into the precipitate, and then the precipitate was pyrolyzed as an efficient adsorbent for phosphate removal. By comparing the adsorption effects of adsorbents (XT-300, XT-400, and XT-500) with pyrolysis temperatures of 300 °C, 400 °C, and 500 °C on phosphate in actual phosphorus-containing wastewater and simulated phosphorus-containing wastewater at different adsorbent dosage (4 g/L, 7 g/L, and 10 g/L), it was found that XT-300 had the best performance of adsorption, and the adsorption of phosphate was endothermic and obeyed the Langmuir isotherms and Elovich kinetics. The influence of pH, coexisting anions, and the structure of XT-300 revealed that the removal of phosphate was associated with electrostatic attraction, pore filling, but could not be determined whether it was related to surface precipitation. This study provides a way and method for the recovery and utilization of phosphorus in fruit and vegetable wastewater and proves that the synthetic adsorbent was an efficient phosphorus adsorbent. In the long term, we can try to use the adsorbent after phosphorus adsorption to promote plant growth in agricultural systems.

How Rhodium(I)-Catalyzed Phosphorus(III)-Directed C–H Bond Functionalizations Can Improve the Catalytic Activities of Phosphines

Trivalent-phosphorus-containing molecules are widely used in fields ranging from catalysis to materials science. Efficient catalytic methods for their modifications, providing straightforward access to novel hybrid structures with superior catalytic activities, are highly desired to facilitate reaction improvement or discovery. We have recently developed new methods for synthesizing polyfunctional phosphines by C–C cross-couplings through rhodium-catalyzed C–H bond activation. These methods use a native P(III) atom as a directing group, and can be used in regioselective late-stage functionalization of phosphine ligands. Interestingly, some of the modified phosphines outperform their parents in Pd-catalyzed cross-coupling reactions.1 Introduction2 Early Examples of Transition-Metal-Catalyzed P(III)-Directed C–H Bond Activation/Functionalizations3 Synthesis of Polyfunctional Biarylphosphines by Late-Stage Alkylation: Application in Carboxylation Reactions4 Synthesis of Polyfunctional Biarylphosphines by Late-Stage Alkenylation: Application in Amidation Reactions5 Conclusion

[1]Rotaxanes based on phosphorylated pillar[5]arenes

[1]Rotaxanes based on monosubstituted phosphorus-containing pillar[5]arenes have been synthesized for the first time by the Kabachnik-Fields reaction with good yields. The introduction of bulky phosphoryl function stopper led to formation...

Efficient capture of phosphate from wastewater by a recyclable ionic liquid functionalized polyacrylonitrile fiber: A typical “Release and Catch” mechanism

The enrichment and separation of phosphorus-containing compounds from wastewater can prevent eutrophication and recycle non-renewable resource. Herein, we developed a recyclable functionalized polyacrylonitrile fiber (PANAF-Cl) capable of loading ionic liquid...

INVESTIGATES THE INFLUENCE PHOSPHORUS-NITROGEN-CONTAINING ANTIPYRENES ON THERMAL STABILITY AND FLAME RETARDANCY OF POLYURETHANE FOAM

The paper investigates the influence of melamine and ammonium polyphosphates on thermal degradation and flame retardancy of polyurethane foams (PUFs) composites, based on phosphorus-containing polyol. The limiting oxygen index of PUF was increased from 27,5 to 31,5 vol. % as compared to PUF composites based on phosphorus-containing polyol. The TGA of polyurethane foams demonstrated an increase of the thermal stability. Synthesized polyurethane foams have the highest category of combustion resistance.