ChemInform Abstract: REACTIONS OF HYDRIDE WITH TUNGSTEN COMPLEXES CONTAINING ORGANOSULFUR LIGANDS: SYNTHESIS AND CHARACTERIZATION OF (μ-HYDRIDO)BIS(μ-DIMETHYL SULFIDE)DITUNGSTEN(III) SPECIES

1985 ◽  
Vol 16 (51) ◽  
Author(s):  
P. M. BOORMAN ◽  
K. J. MOYNIHAN ◽  
V. D. PATEL ◽  
J. F. RICHARDSON
Keyword(s):  
Dimethyl Sulfide ◽  
Synthesis And Characterization ◽  
Tungsten Complexes

Synthesis and Characterization of Diorganohydrazido(2–) Tungsten Complexes

2008 ◽  
Vol 47 (11) ◽  
pp. 4457-4462 ◽  
Author(s):  
Jürgen Koller ◽  
Hiral M. Ajmera ◽  
Khalil A. Abboud ◽  
Timothy J. Anderson ◽  
Lisa McElwee-White
Keyword(s):  
Synthesis And Characterization ◽  
Tungsten Complexes

Synthesis and characterization of novel tungsten complexes and their activity in the ROMP of cyclic olefins

Polyhedron ◽  
2012 ◽  
Vol 42 (1) ◽  
pp. 102-109 ◽  
Author(s):  
Saira Nayab ◽  
Wonjin Park ◽  
Hyun Yul Woo ◽  
Ick Kyung Sung ◽  
Woon Sung Hwang ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Tungsten Complexes ◽  
Cyclic Olefins

scholarly journals Synthesis and Characterization of Methoxy-bridged Bis(silylene)tungsten Complexes

2011 ◽  
Vol 4 (1) ◽  
pp. 109 ◽  
Author(s):  
R. Begum ◽  
S. M. S. Islam
Keyword(s):  
Elemental Analysis ◽  
Oxidative Addition ◽  
Metal Center ◽  
Synthesis And Characterization ◽  
29Si Nmr ◽  
Mechanism Of Formation ◽  
Tungsten Complexes ◽  
Plausible Mechanism ◽  
Silylene Complexes

Synthesis of two methoxy bridged bis(silylene) complexes (CpMe4)W(CO)2 {(Et2Si)••OMe••(SiMe2)}(3) and (CpMe)W(CO)2 {(Et2Si)••OMe••(SiMe2)}(4) have been synthesized. Both the compounds contain chiral tungsten center and formed via oxidative addition of an Si-H bond to a coordinatively unsaturated metal center. The complexes were characterized by 1H, 13C, 29Si NMR, IR and elemental analysis. A plausible mechanism of formation is also suggested.Keywords:  Coordinatively unsaturated; Chiral tungsten; Oxidative addition.© 2012 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.doi: http://dx.doi.org/10.3329/jsr.v4i1.7890J. Sci. Res. 4 (1), 109-118 (2012)

Sign in / Sign up

Export Citation Format

Share Document