Abstract The Y_0.4Bi_0.6VO_4 and Y_0.6Bi_0.4VO_4 solid solutions two-phase at x _Bi = 0.95, 0.90, and 0.80 have been formed by the solid-phase synthesis from the initial Y_2O_3, Bi_2O_3, and V_2O_5 oxides burned in air at a temperature of 1173 K for 200 h and their high-temperature heat capacity has been measured in the range of 350–1000 K by differential scanning calorimetry. The thermodynamic properties of the solution solutions have been calculated using the data obtained.
SmFeGe2O7 germanate was obtained by solid-state reactions from stoichiometric mixtures of starting oxides with multistage firing within 1273-1473 K. The effect of temperature on the heat capacity of the compound was studied using differential scanning calorimetry. Based on the dependence Cp = f(T), its thermodynamic properties are calculated.
The Pb10-xNdx(GeO4)2+x(VO4)4-x (x = 0 ‒ 3) compounds with the apatite structure have been synthesized from PbO, Nd2O3, GeO2 and V2O5 oxides by the solid-state synthesis with successive burning in air within 773-1073 K. The high-temperature heat capacity of the compounds obtained was determined by differential scanning calorimetry. The CP = f(T) data have been used to evaluate their thermodynamic properties (enthalpy increment, entropy change, and reduced Gibbs energy).
Синтез, структура и теплофизические свойства оксидов системы YVO_4-BiVO-=SUB=-4-=/SUB=-
