Structure-property relationships are important in the process optimization and fundamental understanding of many polymeric materials, including membranes. Polymer membranes are currently being used for separation, concentration or purification in a wide range of industrial process applications. The process used to manufacture the membrane, and the polymer type, determines the morphology, which influences the membrane transport properties and potential applications. The morphology includes: pore size, shape, distribution and their overall three dimensional arrangement. Microscopical methods are needed to image the structures formed by the various processes, in order to systematically study changes in variables for specific applications.