ChemInform Abstract: Physical Organic Chemistry of Transition-Metal Carbene Complexes. Part 10. Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5Cr=C(OMe)CHR′R′′-Type Fischer Carbene Complexes in Aqueous Acetonitrile.

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Alkyl Groups ◽

Opposing Effects

Physical Organic Chemistry of Transition Metal Carbene Complexes. 10.1Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5CrC(OMe)CHR‘R‘‘-Type Fischer Carbene Complexes in Aqueous Acetonitrile. Analogy to the Nitroalkane Anomaly

10.1021/ja970193z ◽

1997 ◽

Vol 119 (24) ◽

pp. 5583-5590 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

Weitao Sun ◽

Luis Garcia-Río ◽

Kin Yan ◽

Kevin Kittredge

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Alkyl Groups

Physical Organic Chemistry of Transition Metal Carbene Complexes. 22.1Substituent Effects on the Reversible Cyclization of Fischer Carbene Complexes (CO)5WC(SCH2CH2OH)C6H4Z in Aqueous Acetonitrile

Organometallics ◽

10.1021/om010364f ◽

2001 ◽

Vol 20 (16) ◽

pp. 3383-3389 ◽

Cited By ~ 5

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Reversible Cyclization

Physical Organic Chemistry of Transition Metal Carbene Complexes. 18.1Kinetics of Reversible Cyclization of the Fischer Carbene Complexes (CO)5MC(SCH2CH2OH)Ph and (CO)5MC(OCH2CH2OH)Ph (M = Cr, W) in Aqueous Acetonitrile

10.1021/ja993418+ ◽

2000 ◽

Vol 122 (7) ◽

pp. 1352-1359 ◽

Cited By ~ 10

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali ◽

Felice Lu

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Reversible Cyclization

Physical Organic Chemistry of Transition Metal Complexes. 31.†Nucleophilic Attachment of the Malononitrile Anion to Fischer Carbene Complexes

Organometallics ◽

10.1021/om0401051 ◽

2004 ◽

Vol 23 (26) ◽

pp. 6134-6139 ◽

Cited By ~ 10

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic Chemistry of Transition Metal Carbene Complexes. 14.1Thermodynamic Acidity Measurements of Fischer Carbene Complexes in Acetonitrile

10.1021/ja980608w ◽

1998 ◽

Vol 120 (34) ◽

pp. 8632-8639 ◽

Cited By ~ 12

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Mark L. Ragains ◽

Yan Shi ◽

Huan Wang ◽

...

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Carbene Complexes ◽

Fischer Carbene ◽

ChemInform Abstract: Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 14. Thermodynamic Acidity Measurements of Fischer Carbene Complexes in Acetonitrile

ChemInform ◽

10.1002/chin.199849030 ◽

2010 ◽

Vol 29 (49) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

A. E. LEYES ◽

M. L. RAGAINS ◽

Y. SHI ◽

H. WANG ◽

...

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic Chemistry of Transition Metal Carbene Complexes. 8.1Kinetic and Thermodynamic Acidities of Alkoxyalkylcarbene Pentacarbonyl Complexes of Cr, Mo, and W in Aqueous Acetonitrile. Dependence on Metal, Alkyl Group, and Alkoxy Group

Organometallics ◽

10.1021/om960936+ ◽

1997 ◽

Vol 16 (9) ◽

pp. 1926-1932 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Alkyl Group ◽

Alkoxy Group ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

The Physical Organic Chemistry of Fischer Carbene Complexes

ChemInform ◽

10.1002/chin.200325271 ◽

2003 ◽

Vol 34 (25) ◽

Author(s):

Claude F. Bernasconi

Keyword(s):

Organic Chemistry ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic Chemistry of Transition Metal Carbene Complexes. 25. Kinetic and Thermodynamic Acidities of Substituted (Methylthiophenylcarbene)pentacarbonyl Tungsten(0) and (Benzoxymethylcarbene)pentacarbonyl Tungsten(0) in Aqueous Acetonitrile. Evidence for Transition State Imbalances†

10.1021/ja020665w ◽

2002 ◽

Vol 124 (50) ◽

pp. 14968-14976 ◽

Cited By ~ 11

Author(s):

Claude F. Bernasconi ◽

Viola Ruddat

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Transition State ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic Chemistry of Transition Metal Carbene Complexes. 9.1Thermodynamic and Kinetic Acidity of (2-Oxacyclopentylidene)pentacarbonylchromium(0) in Aqueous Acetonitrile

10.1021/ja964069b ◽

1997 ◽

Vol 119 (22) ◽

pp. 5169-5175 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Kinetic Acidity