Physical Organic Chemistry of Transition Metal Carbene Complexes. 10.1Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5CrC(OMe)CHR‘R‘‘-Type Fischer Carbene Complexes in Aqueous Acetonitrile. Analogy to the Nitroalkane Anomaly

Claude F. Bernasconi; Weitao Sun; Luis Garcia-Río; Kin Yan; Kevin Kittredge

doi:10.1021/ja970193z

Physical Organic Chemistry of Transition Metal Carbene Complexes. 10.1Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5CrC(OMe)CHR‘R‘‘-Type Fischer Carbene Complexes in Aqueous Acetonitrile. Analogy to the Nitroalkane Anomaly

Journal of the American Chemical Society ◽

10.1021/ja970193z ◽

1997 ◽

Vol 119 (24) ◽

pp. 5583-5590 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

Weitao Sun ◽

Luis Garcia-Río ◽

Kin Yan ◽

Kevin Kittredge

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Alkyl Groups

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ChemInform Abstract: Physical Organic Chemistry of Transition-Metal Carbene Complexes. Part 10. Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5Cr=C(OMe)CHR′R′′-Type Fischer Carbene Complexes in Aqueous Acetonitrile.

ChemInform ◽

10.1002/chin.199741100 ◽

2010 ◽

Vol 28 (41) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

W. SUN ◽

L. GARCIA-RIO ◽

K. YAN ◽

K. KITTREDGE

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Alkyl Groups ◽

Opposing Effects

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 22.1Substituent Effects on the Reversible Cyclization of Fischer Carbene Complexes (CO)5WC(SCH2CH2OH)C6H4Z in Aqueous Acetonitrile

Organometallics ◽

10.1021/om010364f ◽

2001 ◽

Vol 20 (16) ◽

pp. 3383-3389 ◽

Cited By ~ 5

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Reversible Cyclization

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 18.1Kinetics of Reversible Cyclization of the Fischer Carbene Complexes (CO)5MC(SCH2CH2OH)Ph and (CO)5MC(OCH2CH2OH)Ph (M = Cr, W) in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja993418+ ◽

2000 ◽

Vol 122 (7) ◽

pp. 1352-1359 ◽

Cited By ~ 10

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali ◽

Felice Lu

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Reversible Cyclization

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Physical Organic Chemistry of Transition Metal Complexes. 31.†Nucleophilic Attachment of the Malononitrile Anion to Fischer Carbene Complexes

Organometallics ◽

10.1021/om0401051 ◽

2004 ◽

Vol 23 (26) ◽

pp. 6134-6139 ◽

Cited By ~ 10

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 14.1Thermodynamic Acidity Measurements of Fischer Carbene Complexes in Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja980608w ◽

1998 ◽

Vol 120 (34) ◽

pp. 8632-8639 ◽

Cited By ~ 12

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Mark L. Ragains ◽

Yan Shi ◽

Huan Wang ◽

...

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic

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ChemInform Abstract: Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 14. Thermodynamic Acidity Measurements of Fischer Carbene Complexes in Acetonitrile

ChemInform ◽

10.1002/chin.199849030 ◽

2010 ◽

Vol 29 (49) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

A. E. LEYES ◽

M. L. RAGAINS ◽

Y. SHI ◽

H. WANG ◽

...

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 8.1Kinetic and Thermodynamic Acidities of Alkoxyalkylcarbene Pentacarbonyl Complexes of Cr, Mo, and W in Aqueous Acetonitrile. Dependence on Metal, Alkyl Group, and Alkoxy Group

Organometallics ◽

10.1021/om960936+ ◽

1997 ◽

Vol 16 (9) ◽

pp. 1926-1932 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Alkyl Group ◽

Alkoxy Group ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

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The Physical Organic Chemistry of Fischer Carbene Complexes

ChemInform ◽

10.1002/chin.200325271 ◽

2003 ◽

Vol 34 (25) ◽

Author(s):

Claude F. Bernasconi

Keyword(s):

Organic Chemistry ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 25. Kinetic and Thermodynamic Acidities of Substituted (Methylthiophenylcarbene)pentacarbonyl Tungsten(0) and (Benzoxymethylcarbene)pentacarbonyl Tungsten(0) in Aqueous Acetonitrile. Evidence for Transition State Imbalances†

Journal of the American Chemical Society ◽

10.1021/ja020665w ◽

2002 ◽

Vol 124 (50) ◽

pp. 14968-14976 ◽

Cited By ~ 11

Author(s):

Claude F. Bernasconi ◽

Viola Ruddat

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Transition State ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

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Physical Organic Chemistry of Transition Metal Carbene Complexes. 9.1Thermodynamic and Kinetic Acidity of (2-Oxacyclopentylidene)pentacarbonylchromium(0) in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja964069b ◽

1997 ◽

Vol 119 (22) ◽

pp. 5169-5175 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Kinetic Acidity

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