ChemInform Abstract: Palladium-Catalyzed Formation and Stereoselective Isomerization of 5-Vinyloxazolines. Application to the Formal Synthesis of (S,S)-4-Amino-3-hydroxy-5-phenylpentanoic Acid.

ChemInform ◽  
2010 ◽  
Vol 29 (31) ◽  
pp. no-no
Author(s):  
G. R. COOK ◽  
P. S. SHANKER
Keyword(s):  
Formal Synthesis ◽  
Palladium Catalyzed

ChemInform Abstract: Stereoselective β-C-Glycosylation by a Palladium-Catalyzed Decarboxylative Allylation: Formal Synthesis of Aspergillide A.

ChemInform ◽  
2013 ◽  
Vol 44 (40) ◽  
pp. no-no
Author(s):  
Jing Zeng ◽  
Jimei Ma ◽  
Shaohua Xiang ◽  
Shuting Cai ◽  
Xue-Wei Liu
Keyword(s):  
Formal Synthesis ◽  
Palladium Catalyzed ◽  
Decarboxylative Allylation

ChemInform Abstract: Formal Synthesis of Nitidine Through Palladium-Catalyzed Isocoumarin Synthesis.

ChemInform ◽  
2010 ◽  
Vol 27 (15) ◽  
pp. no-no
Author(s):  
T. MINAMI ◽  
A. NISHIMOTO ◽  
M. HANAOKA
Keyword(s):  
Formal Synthesis ◽  
Palladium Catalyzed

ChemInform Abstract: Combined Metalation-Palladium-Catalyzed Cross Coupling Strategies. A Formal Synthesis of the Marine Alkaloid Amphimedine.

ChemInform ◽  
2010 ◽  
Vol 26 (30) ◽  
pp. no-no
Author(s):  
F. GUILLIER ◽  
F. NIVOLIERS ◽  
A. GODARD ◽  
F. MARSAIS ◽  
G. QUEGUINER ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Formal Synthesis ◽  
Marine Alkaloid ◽  
Palladium Catalyzed ◽  
Coupling Strategies

scholarly journals Unified strategy for the synthesis of C-aryl glycosides

2003 ◽  
Vol 75 (1) ◽  
pp. 63-70 ◽  
Author(s):  
S. F. Martin
Keyword(s):  
Unified Approach ◽  
Formal Synthesis ◽  
Palladium Catalyzed ◽  
Acid Catalyzed ◽  
Integrated Approaches ◽  
Aryl Glycosides ◽  
Aryl Glycoside

A unified approach for the synthesis of the four major groups of C-aryl glycosides has been developed. The strategy incorporates two integrated approaches, the first of which features the [4+2] cycloaddition of a glycosyl furan with a substituted benzyne followed by the acid-catalyzed opening of the resultant adduct. The second route involves the sequential palladium-catalyzed opening of a benzyne-furan cycloadduct with an iodo glycal followed by oxidation of the resultant dihydronaphthol ring and reduction of the glycal moiety. The utility of this strategy has been established by a concise formal synthesis of the C-aryl glycoside antibiotic galtamycinone.

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