ChemInform Abstract: Enantioselective Hydrogenation of α-Dehydroamino Acid Esters Catalyzed by Rhodium Complexes with Chiral Bisaminophosphine Ligands.

ChemInform ◽  
2010 ◽  
Vol 41 (35) ◽  
pp. no-no
Author(s):  
Xianfeng Sun ◽  
Wei Li ◽  
Le Zhou ◽  
Xumu Zhang
ChemInform ◽  
2004 ◽  
Vol 35 (46) ◽  
Author(s):  
Hanmin Huang ◽  
Xiongcai Liu ◽  
Song Chen ◽  
Huilin Chen ◽  
Zhuo Zheng

2004 ◽  
Vol 15 (13) ◽  
pp. 2011-2019 ◽  
Author(s):  
Hanmin Huang ◽  
Xiongcai Liu ◽  
Song Chen ◽  
Huilin Chen ◽  
Zhuo Zheng

1990 ◽  
Vol 68 (8) ◽  
pp. 1425-1436 ◽  
Author(s):  
Oliver E. Edwards ◽  
Werner Rank

Photolysis of 2-alkyl-2-azido-3-oxobutanoic esters and amides gave products resulting from alkyl or acyl migration onto nitrogen. The resulting ketimimes could be isolated in moderate purity, but the N-acyl imines were rapidly converted into solvation products or enamides (N-acetyl dehydroamino acid esters) resulting from double bond migration. Mechanisms for formation of these products are discussed. The N-(2-azido-2-methyl-3-oxobutanoyl) derivative of the diketopiperazine from L-valyl-L-proline gave a stereoisomer of the cyclol tripeptide unit of ergovaline. Keywords: N-acyl imines, mechanism of 2-azido-3-keto ester photolysis, cyclol tripeptide synthesis, ergovaline.


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