ChemInform Abstract: Green and Scalable Procedure for Extremely Fast Ligandless Suzuki-Miyaura Cross-Coupling Reactions in Aqueous IPA Using Solid-Supported Pd in Continuous Flow.

ChemInform ◽  
2014 ◽  
Vol 45 (50) ◽  
pp. no-no
Author(s):  
Carlos Mateos ◽  
Juan A. Rincon ◽  
Beatriz Martin-Hidalgo ◽  
Jose Villanueva
Keyword(s):  
Continuous Flow ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Supported Pd

Pyridinyl functionalized MCM-48 supported highly active heterogeneous palladium catalyst for cross-coupling reactions

RSC Advances ◽  
2015 ◽  
Vol 5 (25) ◽  
pp. 19630-19637 ◽  
Author(s):  
Shaheen M. Sarkar ◽  
Md. Lutfor Rahman ◽  
Mashitah Mohd Yusoff
Keyword(s):  
Palladium Catalyst ◽  
Cross Coupling ◽  
Significant Loss ◽  
Pd Catalyst ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Highly Active ◽  
Supported Pd ◽  
Heterogeneous Palladium Catalyst

Pyridinyl functionalized MCM-48-supported Pd-catalyst efficiently (0.013–0.025 mol%) promoted Heck, Suzuki and Sonogashira cross-coupling reactions. Moreover, the catalyst was reused five times without significant loss of its activity.

Recent Applications of Continuous Flow in Homogeneous Palladium Catalysis

Synthesis ◽  
2020 ◽  
Vol 52 (23) ◽  
pp. 3511-3529 ◽  
Author(s):  
Peter Koóš ◽  
Martin Markovič ◽  
Pavol Lopatka ◽  
Tibor Gracza
Keyword(s):  
Organic Synthesis ◽  
Continuous Flow ◽  
Palladium Catalysis ◽  
Flow Chemistry ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Flow Conditions ◽  
Cross Coupling Reactions ◽  
Continuous Flow Chemistry ◽  
Oxidative Transformations

Considerable advances have been made using continuous flow chemistry as an enabling tool in organic synthesis. Consequently, the number of articles reporting continuous flow methods has increased significantly in recent years. This review covers the progress achieved in homogeneous palladium catalysis using continuous flow conditions over the last five years, including C–C/C–N cross-coupling reactions, carbonylations and reductive/oxidative transformations.1 Introduction2 C–C Cross-Coupling Reactions3 C–N Coupling Reactions4 Carbonylation Reactions5 Miscellaneous Reactions6 Key to Schematic Symbols7 Conclusion

scholarly journals Cover Picture: Dendrimer-Encapsulated Palladium Nanoparticles for Continuous-Flow Suzuki-Miyaura Cross-Coupling Reactions (ChemCatChem 6/2015)

ChemCatChem ◽  
2015 ◽  
Vol 7 (6) ◽  
pp. 875-875
Author(s):  
Roberto Ricciardi ◽  
Jurriaan Huskens ◽  
Michael Holtkamp ◽  
Uwe Karst ◽  
Willem Verboom
Keyword(s):  
Palladium Nanoparticles ◽  
Continuous Flow ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Dendrimer-encapsulated Pd nanoparticles as catalysts for C–C cross-couplings in flow microreactors

2015 ◽  
Vol 13 (17) ◽  
pp. 4953-4959 ◽  
Author(s):  
Roberto Ricciardi ◽  
Jurriaan Huskens ◽  
Willem Verboom
Keyword(s):  
Continuous Flow ◽  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Flow Microreactors

Dendrimer-encapsulated Pd nanoparticles anchored within continuous flow microreactors are efficient for C–C cross-coupling reactions. This is witnessed by the good catalytic performance for the Heck–Cassar and Suzuki–Miyaura couplings.

Heck, Suzuki and Sonogashira cross-coupling reactions using ppm level of SBA-16 supported Pd-complex

2015 ◽  
Vol 39 (5) ◽  
pp. 3564-3570 ◽  
Author(s):  
Shaheen M. Sarkar ◽  
Md. Lutfor Rahman ◽  
Mashitah Mohd Yusoff
Keyword(s):  
Cross Coupling ◽  
Significant Loss ◽  
Coupling Reactions ◽  
Reaction Conditions ◽  
Cross Coupling Reactions ◽  
Ppm Level ◽  
Supported Pd

SBA-16-supported Pd-complex (100–500 mol ppm) catalyzed the Heck, Suzuki and Sonongashira cross-coupling reactions under mild reaction conditions without a significant loss of its activity.

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