A Robust Ionic Liquid as Reaction Medium and Efficient Organocatalyst for Carbon Dioxide Fixation

ChemSusChem ◽  
2008 ◽  
Vol 1 (1-2) ◽  
pp. 67-70 ◽  
Author(s):  
Wing-Leung Wong ◽  
Pak-Ho Chan ◽  
Zhong-Yuan Zhou ◽  
Kam-Han Lee ◽  
Kwong-Chak Cheung ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Reaction Medium ◽  
Carbon Dioxide Fixation

Distillable ionic liquids for a new multicomponent reaction

2007 ◽  
Vol 79 (11) ◽  
pp. 1869-1877 ◽  
Author(s):  
Anthony E. Rosamilia ◽  
Christopher R. Strauss ◽  
Janet L. Scott
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Multicomponent Reaction ◽  
Reaction Medium ◽  
Building Blocks ◽  
Substituted Anilines ◽  
Reaction Sequence ◽  
Unsaturated Ketones ◽  
Direct Preparation

Adducts of dimethylamine and carbon dioxide form a "distillable ionic liquid" (DIMCARB) that may used as both a reaction medium and catalyst in the direct, atom-economical synthesis of useful synthetic building blocks, such as mono-condensed α,β-unsaturated ketones. The utilization of such building blocks in the synthesis of two new classes of versatile macrocycles, by a sequence of condensation reactions (H2O by-product), is described. Investigation into the mechanism of action of DIMCARB catalysis and observation of an aniline impurity arising from a competing reaction sequence led to development of a new multicomponent reaction for the direct preparation of 2- or 4-substituted anilines. Some of the macrocycles and anilines are, respectively, supramolecular host compounds and ligands for the preparation of metal complexes.

scholarly journals CARBON DIOXIDE FIXATION IN ISOCITRIC ACID

1947 ◽  
Vol 170 (2) ◽  
pp. 461-465
Author(s):  
Santiago Grisolia ◽  
Birgit Vennesland
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Fixation ◽  
Isocitric Acid

scholarly journals THE PREPARATION OF C14-LABELED BIOTIN AND A STUDY OF ITS STABILITY DURING CARBON DIOXIDE FIXATION

1949 ◽  
Vol 180 (1) ◽  
pp. 299-305 ◽  
Author(s):  
Donald B. Melville ◽  
John G. Pierce ◽  
C.W.H. Partridge
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Fixation

scholarly journals BIOSYNTHESIS OF TRICARBOXYLIC ACIDS BY CARBON DIOXIDE FIXATION

1948 ◽  
Vol 174 (1) ◽  
pp. 123-132 ◽  
Author(s):  
Severo Ochoa ◽  
Erna Weisz-Tabori
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Fixation

scholarly journals The Discovery of Heterotrophic Carbon Dioxide Fixation by Harland G.Wood

2005 ◽  
Vol 280 (18) ◽  
pp. 155-157
Author(s):  
Nicole Kresge ◽  
Robert D. Simoni ◽  
Robert L. Hill
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Fixation
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