Selective Aerobic Oxidation of 5-(Hydroxymethyl)furfural to 5-Formyl-2-furancarboxylic Acid in Water

ChemSusChem ◽  
2016 ◽  
Vol 9 (10) ◽  
pp. 1096-1100 ◽  
Author(s):  
Maria Ventura ◽  
Michele Aresta ◽  
Angela Dibenedetto
Keyword(s):  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Selective Aerobic Oxidation

Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water

2018 ◽  
Vol 20 (17) ◽  
pp. 3921-3926 ◽  
Author(s):  
Maria Ventura ◽  
Francesco Nocito ◽  
Elvira de Giglio ◽  
Stefania Cometa ◽  
Angela Altomare ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Mixed Oxides ◽  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation

The selective oxidation of 5-HMF towards 2,5-furandicarboxylic acid (FDCA) has been achieved with 99% yield in water, using oxygen as the oxidant over CuO·MnO2·CeO2 mixed oxides.

scholarly journals Supported gold- and silver-based catalysts for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to 2,5-furandicarboxylic acid and 5-hydroxymethyl-2-furancarboxylic acid

2018 ◽  
Vol 20 (15) ◽  
pp. 3530-3541 ◽  
Author(s):  
Oliver R. Schade ◽  
Kai F. Kalz ◽  
Dominik Neukum ◽  
Wolfgang Kleist ◽  
Jan-Dierk Grunwaldt
Keyword(s):  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Highly Active ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation ◽  
Supported Gold ◽  
First Time

The oxidation of HMF is performed using highly active heterogeneous gold- and, for the first time, silver-based catalysts.

Highly Selective Aerobic Oxidation of 5-Hydroxymethyl Furfural into 2,5-Diformylfuran over Mn-Co Binary Oxides

2017 ◽  
Vol 2 (23) ◽  
pp. 6632-6639 ◽  
Author(s):  
Zhenyou Gui ◽  
Shunmugavel Saravanamurugan ◽  
Wenrong Cao ◽  
Leonhard Schill ◽  
Lifang Chen ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Binary Oxides ◽  
Selective Aerobic Oxidation

scholarly journals Selective Aerobic Oxidation of 5‐(Hydroxymethyl)furfural over Heterogeneous Silver‐Gold Nanoparticle Catalysts

2020 ◽  
Vol 362 (24) ◽  
pp. 5681-5696
Author(s):  
Oliver R. Schade ◽  
Frederic Stein ◽  
Sven Reichenberger ◽  
Abhijeet Gaur ◽  
Erisa Saraҫi ◽  
...  
Keyword(s):  
Gold Nanoparticle ◽  
Aerobic Oxidation ◽  
Nanoparticle Catalysts ◽  
Hydroxymethyl Furfural ◽  
Selective Aerobic Oxidation

Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

2018 ◽  
Vol 8 (23) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xu Jin ◽  
Rengui Li ◽  
Yue Zhao ◽  
Xiaodan Liu ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Spatial Separation ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

scholarly journals Self-Exfoliated Synthesis of Transition Metal Phosphate Nanolayers for Selective Aerobic Oxidation of Ethyl Lactate to Ethyl Pyruvate

ACS Catalysis ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 3958-3967
Author(s):  
Wei Zhang ◽  
Paula Oulego ◽  
Sandeep K. Sharma ◽  
Xiu-Lin Yang ◽  
Lain-Jong Li ◽  
...  
Keyword(s):  
Transition Metal ◽  
Ethyl Pyruvate ◽  
Aerobic Oxidation ◽  
Ethyl Lactate ◽  
Metal Phosphate ◽  
Selective Aerobic Oxidation

On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

2014 ◽  
Vol 3 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Hannes Alex ◽  
Norbert Steinfeldt ◽  
Klaus Jähnisch ◽  
Matthias Bauer ◽  
Sandra Hübner
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
X Ray ◽  
X Ray Scattering ◽  
Oxidation Of Benzyl Alcohol ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

High-Activity, Single-Site Mesoporous Pd/Al2O3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols

2007 ◽  
Vol 119 (45) ◽  
pp. 8747-8750 ◽  
Author(s):  
Simon F. J. Hackett ◽  
Rik M. Brydson ◽  
Mhairi H. Gass ◽  
Ian Harvey ◽  
Andrew D. Newman ◽  
...  
Keyword(s):  
High Activity ◽  
Aerobic Oxidation ◽  
Single Site ◽  
Allylic Alcohols ◽  
Selective Aerobic Oxidation
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