scholarly journals The Thermochemistry of Alkyne Insertion into a Palladacycle outlines the Solvation Conundrum in DFT.

2021 ◽  
Author(s):  
Milan R. Milovanović ◽  
Mélanie Boucher ◽  
Yann Cornaton ◽  
Snežana D. Zarić ◽  
Michel Pfeffer ◽  
...  
Keyword(s):  
Alkyne Insertion

Palladium-Catalyzed Alkyne Insertion/Reduction Route to Trisubstituted Olefins

2013 ◽  
Vol 15 (17) ◽  
pp. 4362-4365 ◽  
Author(s):  
Erin R. Fruchey ◽  
Brendan M. Monks ◽  
Andrea M. Patterson ◽  
Silas P. Cook
Keyword(s):  
Trisubstituted Olefins ◽  
Palladium Catalyzed ◽  
Alkyne Insertion

Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C–H Bonds

2013 ◽  
Vol 78 (16) ◽  
pp. 8098-8104 ◽  
Author(s):  
Masaki Itoh ◽  
Yuto Hashimoto ◽  
Koji Hirano ◽  
Tetsuya Satoh ◽  
Masahiro Miura
Keyword(s):  
Alkyne Insertion

P–C reductive elimination in Ru(ii) complexes to convert triarylphosphine ligands into five- or six-membered phosphacycles

2018 ◽  
Vol 54 (42) ◽  
pp. 5357-5360 ◽  
Author(s):  
Takuya Kuwabara ◽  
Takahiro Kato ◽  
Kouichi Takano ◽  
Shintaro Kodama ◽  
Yuuka Manabe ◽  
...  
Keyword(s):  
Reductive Elimination ◽  
Alkyne Insertion

η4-Phosphacycle complexes were obtained from PPh2Ar (Ar = Ph, 1-Naph) via cyclometallation, alkyne insertion and P–C reductive elimination at a Ru centre.

Formal Alkyne Insertion into Alkoxycarbene Complexes: Simple Access to Enantiopure Group 6 Alkynyl(alkoxy)carbene Complexes.

ChemInform ◽  
2005 ◽  
Vol 36 (49) ◽  
Author(s):  
Jose Barluenga ◽  
Ramon Bernardo de la Rua ◽  
Diana de Saa ◽  
Alfredo Ballesteros ◽  
Miguel Tomas
Keyword(s):  
Carbene Complexes ◽  
Group 6 ◽  
Alkyne Insertion

ON THE MECHANISM OF PHOTOCHEMICAL ALKYNE INSERTION INTO CYCLOPENTADIENYLIRONDICARBONYL DIMER: ALKYNE ADDITION TO A “TIED-BACK” Cp-Fe DIMER

1994 ◽  
Vol 32 (1-3) ◽  
pp. 249-259 ◽  
Author(s):  
Steven D. McKee ◽  
Jeanette A. Krause ◽  
Diane M. Lunder ◽  
Bruce E. Bursten
Keyword(s):  
Alkyne Insertion ◽  
Alkyne Addition
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