Transition-Metal-Catalyzed Transformations of 1-Alkenylpropargyl Alcohols and Esters: Valuable Cascade Reactions for Increasing Structural Complexity

2016 ◽  
Vol 2017 (5) ◽  
pp. 940-949 ◽  
Author(s):  
Edgar Haak
Keyword(s):  
Transition Metal ◽  
Structural Complexity ◽  
Cascade Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Reductive Cross-Coupling of Vinyl Electrophiles

Synthesis ◽  
2020 ◽  
Vol 52 (24) ◽  
pp. 3751-3763 ◽  
Author(s):  
Xing-Zhong Shu ◽  
Xiaobo Pang ◽  
Xuejing Peng
Keyword(s):  
Transition Metal ◽  
Heck Reaction ◽  
Structural Complexity ◽  
Cross Coupling ◽  
Heck Reactions ◽  
Promising Tool ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The synthesis of alkenes (olefins) is a central subject in the synthetic community. The transition-metal-catalyzed reductive cross-coupling of vinyl electrophiles has emerged as a promising tool to produce alkenes with improved flexibility, structural complexity, and functionality tolerance. In this review, we summarized the progress in this field with respect to cross-electrophile couplings and reductive Heck reactions using vinyl electrophiles.1 Introduction2 Cross-Electrophile Coupling of Vinyl Electrophiles3 Reductive Heck Reaction of Vinyl Electrophiles4 Summary and Outlook

Complex Polycyclic Molecules from Acyclic Precursors via Transition Metal Catalyzed Cascade Reactions

ChemInform ◽  
2007 ◽  
Vol 38 (38) ◽  
Author(s):  
Corinne Aubert ◽  
Louis Fensterbank ◽  
Vincent Gandon ◽  
Max Malacria
Keyword(s):  
Transition Metal ◽  
Cascade Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed
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