scholarly journals Ge−Fe Carbonyl Cluster Compounds: Ionic Liquids‐Based Synthesis, Structures, and Properties

ChemistryOpen ◽  
2020 ◽  
Author(s):  
Silke Wolf ◽  
Alexander Egeberg ◽  
Jens Treptow ◽  
Claus Feldmann
Keyword(s):  
Ionic Liquids ◽  
Cluster Compounds ◽  
Carbonyl Cluster ◽  
Structures And Properties

Structures and Properties of Luminescent Pentanitratoeuropate(III) Ionic Liquids

2014 ◽  
Vol 2015 (3) ◽  
pp. 542-551 ◽  
Author(s):  
Ying Zhao ◽  
Ling He ◽  
Ning Tang ◽  
Song Qin ◽  
Guo-Hong Tao ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Structures And Properties

Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine — Novel coordination modes for 2-imidopyridines

2006 ◽  
Vol 84 (2) ◽  
pp. 105-110 ◽  
Author(s):  
Javier A Cabeza ◽  
Ignacio del Río ◽  
Pablo García-Álvarez ◽  
Daniel Miguel
Keyword(s):  
Metal Atom ◽  
Cluster Compounds ◽  
Carbonyl Cluster ◽  
Amido Ligands ◽  
Ruthenium Cluster ◽  
Coordination Type ◽  
Metal Atoms ◽  
Pyridine Nitrogen ◽  
Cluster 2 ◽  
Reflux Temperature

The hexanuclear ruthenium cluster [Ru6(µ3-H)2(µ-H)2(µ4-κ2-ampy)2(CO)14] (1) and the octanuclear one [Ru8(µ-H)(µ4-κ2-ampy)3(µ3-κ2-Hampy)(µ-CO)2(CO)15] (2) have been prepared by treating [Ru6(µ3-H)2(µ5-κ2-ampy)(µ-CO)2(CO)14] with 2-amino-6-methylpyridine (H2ampy) in decane at reflux temperature. Their metal atoms are supported by ligands that derive from the activation of one (complex 2) or both N—H bonds (complexes 1 and 2) of the H2ampy amino fragment. Both contain at least one ampy ligand featuring an unprecedented coordination type: the imido N atom caps a triangle of metal atoms while the pyridine nitrogen is attached to an additional metal atom. One of the ampy ligands of cluster 2 also displays another unprecedented coordination type: it caps a distorted square of metal atoms through the imido N atom while the pyridine nitrogen is attached to one of the atoms included in that square.Key words: ruthenium, cluster compounds, amido ligands, imido ligands.

scholarly journals Heterometallic nitrido cluster compounds: Synthesis and characterizations of the first nitrido-containing ruthenium-gold and ruthenium-copper carbonyl cluster complexes

2019 ◽  
Vol 898 ◽  
pp. 120872 ◽  
Author(s):  
Richard D. Adams ◽  
Perry J. Pellechia ◽  
Mark D. Smith ◽  
Jonathan D. Tedder ◽  
Nutan D. Wakdikar
Keyword(s):  
Cluster Compounds ◽  
Carbonyl Cluster ◽  
Cluster Complexes

Syntheses, Structures, and Properties of a Series of Metal Ion-Containing Dialkylimidazolium Ionic Liquids

2007 ◽  
Vol 80 (12) ◽  
pp. 2365-2374 ◽  
Author(s):  
Chongmin Zhong ◽  
Takehiko Sasaki ◽  
Akiko Jimbo-Kobayashi ◽  
Emiko Fujiwara ◽  
Akiko Kobayashi ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Metal Ion ◽  
Structures And Properties

Intramolecular Dynamics of Tetranuclear Iridium Carbonyl Cluster Compounds. Part V. Polysubstituted derivatives of [Ir4(CO)12]

1994 ◽  
Vol 77 (3) ◽  
pp. 754-770 ◽  
Author(s):  
Andr�s Strawczynski ◽  
Chris Hall ◽  
Giacomo Bondietti ◽  
Renzo Ros ◽  
Raymond Roulet
Keyword(s):  
Cluster Compounds ◽  
Carbonyl Cluster ◽  
Intramolecular Dynamics ◽  
Derivatives Of

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds

1994 ◽  
Vol 227 (2) ◽  
pp. 241-246 ◽  
Author(s):  
S.F.A. Kettle ◽  
E. Diana ◽  
R. Rossetti ◽  
P.L. Stanghellini ◽  
R. Della Pergola ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Molecular Geometry ◽  
Cluster Compounds ◽  
Carbonyl Cluster ◽  
Carbonyl Groups ◽  
Metal Carbonyl Cluster
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