Anionic polymerization of 1,3-cyclohexadiene with alkyllithium/amine system in an aromatic hydrocarbon solvent: Predominant formation of 1,2-addition product

2008 ◽  
Vol 46 (19) ◽  
pp. 6604-6611 ◽  
Author(s):  
Itaru Natori ◽  
Shizue Natori
Keyword(s):  
Aromatic Hydrocarbon ◽  
Anionic Polymerization ◽  
Addition Product ◽  
Predominant Formation ◽  
Hydrocarbon Solvent ◽  
Amine System

Limonene as a renewable unsaturated hydrocarbon solvent for living anionic polymerization of β-myrcene

2021 ◽  
Author(s):  
Akhil Dev ◽  
Alexander Rösler ◽  
Helmut Schlaad
Keyword(s):  
Anionic Polymerization ◽  
Room Temperature ◽  
Unsaturated Hydrocarbon ◽  
Living Anionic Polymerization ◽  
Hydrocarbon Solvent

The acyclic monoterpene β-myrcene is polymerized by anionic polymerization at room temperature using sec-butyllithium as the initiator and the cyclic monoterpene DL-limonene as an unsaturated hydrocarbon solvent. The polymerization is...

The tissue distribution and clearance of Aerotex 3470, an aromatic hydrocarbon solvent

Chemosphere ◽  
1978 ◽  
Vol 7 (7) ◽  
pp. 607-614 ◽  
Author(s):  
J. Sparling ◽  
B. Chittim ◽  
B.S. Clegg ◽  
S. Safe ◽  
J.F.S. Crocker
Keyword(s):  
Aromatic Hydrocarbon ◽  
Tissue Distribution ◽  
Hydrocarbon Solvent

Living Anionic Polymerization of Benzofulvene in Hydrocarbon Solvent

2015 ◽  
Vol 350 (1) ◽  
pp. 55-66 ◽  
Author(s):  
Yuki Kosaka ◽  
Raita Goseki ◽  
Susumu Kawauchi ◽  
Takashi Ishizone
Keyword(s):  
Anionic Polymerization ◽  
Living Anionic Polymerization ◽  
Hydrocarbon Solvent

scholarly journals High Temperature Thermoplastic Elastomers Synthesized by Living Anionic Polymerization in Hydrocarbon Solvent at Room Temperature

2016 ◽  
Vol 49 (7) ◽  
pp. 2646-2655 ◽  
Author(s):  
Weiyu Wang ◽  
Ralf Schlegel ◽  
Benjamin T. White ◽  
Katherine Williams ◽  
Dimitry Voyloy ◽  
...  
Keyword(s):  
High Temperature ◽  
Anionic Polymerization ◽  
Room Temperature ◽  
Thermoplastic Elastomers ◽  
Living Anionic Polymerization ◽  
Hydrocarbon Solvent

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

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