Excited states of transition metal compounds: Quantum chemistry of relaxation effects

2003 ◽  
Vol 96 (2) ◽  
pp. 116-122 ◽  
Author(s):  
V. I. Baranovski ◽  
O. O. Lubimova
Keyword(s):  
Transition Metal ◽  
Quantum Chemistry ◽  
Excited States ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Relaxation Effects

scholarly journals Light-induced catalytic and cytotoxic properties of phosphorescent transition metal compounds with a d 8 electronic configuration

2013 ◽  
Vol 371 (1995) ◽  
pp. 20120126 ◽  
Author(s):  
Wai-Pong To ◽  
Taotao Zou ◽  
Raymond Wai-Yin Sun ◽  
Chi-Ming Che
Keyword(s):  
Transition Metal ◽  
Excited States ◽  
Electronic Configuration ◽  
Transition Metal Compounds ◽  
Triplet States ◽  
Oxygen Species ◽  
Bimolecular Reactions ◽  
Metal Compounds ◽  
Light Emitting ◽  
Triplet Excited States

Transition metal compounds are well documented to have diverse applications such as in catalysis, light-emitting materials and therapeutics. In the areas of photocatalysis and photodynamic therapy, metal compounds of heavy transition metals are highly sought after because they can give rise to triplet excited states upon photoexcitation. The long lifetimes (more than 1 μs) of the triplet states of transition metal compounds allow for bimolecular reactions/processes such as energy transfer and/or electron transfer to occur. Reactions of triplet excited states of luminescent metal compounds with oxygen in cells may generate reactive oxygen species and/or induce damage to DNA, leading to cell death. This article recaps the recent findings on photochemical and phototoxic properties of luminescent platinum(II) and gold(III) compounds both from the literature and experimental results from our group.

Performance of TD-DFT for Excited States of Open-Shell Transition Metal Compounds

2017 ◽  
Vol 121 (20) ◽  
pp. 3929-3942 ◽  
Author(s):  
Bingbing Suo ◽  
Kaiyuan Shen ◽  
Zhendong Li ◽  
Wenjian Liu
Keyword(s):  
Transition Metal ◽  
Excited States ◽  
Open Shell ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Td Dft

Superconductivity of some transition metal compounds

1980 ◽  
Vol 34 (1) ◽  
pp. 45-50 ◽  
Author(s):  
A.Nørlund Christensen ◽  
S.E. Rasmussen ◽  
G. Thirup
Keyword(s):  
Transition Metal ◽  
Transition Metal Compounds ◽  
Metal Compounds
Sign in / Sign up

Export Citation Format

Share Document