Theoretical study of solvent influence on the electronic absorption and emission spectra of kynurenine

2010 ◽  
Vol 111 (14) ◽  
pp. 3799-3804 ◽  
Author(s):  
Enrico Benassi ◽  
Peter S. Sherin





1981 ◽  
Vol 12 (18) ◽  
Author(s):  
C. PARKANYI ◽  
G. VERNIN ◽  
M. JULLIARD ◽  
J. METZGER




2010 ◽  
Vol 14 (09) ◽  
pp. 793-803 ◽  
Author(s):  
Maria Pia Donzello ◽  
Elisa Viola ◽  
Larisa A. Tomachinskaya ◽  
Claudio Ercolani ◽  
Maddalena Corsini ◽  
...  

New styryl-substituted tetrapyrazinoporphyrazines [St8PyzPzM] (M = 2NaI , MgII(H2O) and ZnII ; St = -CH=CHAr , where Ar = phenyl or cumyl) were prepared by template cyclotetramerization of 5,6-distyrylpyrazine-2,3-dicarbonitriles available from condensation of diaminomaleodinitrile with the substituted cinnamils (StCO)2 obtained from biacetyl and arylaldehydes ArCHO . The new porphyrazine macrocycles were characterized by electronic absorption and emission spectra, which provide evidence of efficient π-interaction of the peripheral styryl moieties with the central pyrazinoporphyrazine framework. The electronic excitation of the stylbenoid chromophore in the near UV-region (400 nm) leads to strong emission of the porphyrazine chromophore near 700 nm, allowing to consider the styryl-substituted porphyrazines as efficient light-harvesting species. Their spectral properties and electrochemical behavior are compared with those of stylbenoid phthalocyanines and peripherally substituted tetrapyrazinoporphyrazines.



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