The heats of mixing in the system benzene-ethylene dichloride

A calorimeter has been designed for measuring the heats of mixing of binary liquid systems, which eliminates the need to correct for changes in the composition of the vapour phase on mixing. Improved accuracy has thus been obtained. Heats of mixing have been measured for the three binary systems formed from the three components carbon tetrachloride, chloroform and methylene chloride, and also for the systems benzene + carbon tetrachloride and benzene + ethylene dichloride. Reports that the last system is ideal have been disproved.

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Heats of mixing of Alcohol solutions

Australian Journal of Chemistry ◽

10.1071/ch9550361 ◽

1955 ◽

Vol 8 (3) ◽

pp. 361

Author(s):

I. Brown ◽

W Fock

Keyword(s):

Carbon Tetrachloride ◽

Composition Range ◽

Ethylene Dichloride ◽

Binary Liquid ◽

Heats Of Mixing ◽

Liquid Systems

A calorimeter for the measurement of the heats of mixing of binary liquid systems at temperatures from 20 to 45 �C is described. Heats of mixing have been measured for approximately equimolar mixtures of benzene+carbon tetrachloride at 25 �C, benzene+ethylene dichloride at 25 �C, acetone+chloroform at 25 �C, and ethanol+-carbon tetrachloride at 45 �C. Measurements have been made at intervals over the whole composition range of the systems ethanol+2,2,4-trimethylpentane at 25 �C and ethanol+benzene at 45 �C.

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Liver Fibrosis Associated with Potential Vinyl Chloride and Ethylene Dichloride Exposure from the Petrochemical Industry

SSRN Electronic Journal ◽

10.2139/ssrn.3539692 ◽

2020 ◽

Author(s):

Tzu-Hsuen Yuan ◽

Jun-Lin Chen ◽

Ruei-Hao Shie ◽

Yen-Po Yeh ◽

Chang-Chuan Chan

Keyword(s):

Liver Fibrosis ◽

Vinyl Chloride ◽

Petrochemical Industry ◽

Ethylene Dichloride

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Heats of mixing of butanone and chloroform with alkanes: Ternary systems

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19780837 ◽

1978 ◽

Vol 43 (3) ◽

pp. 837-847 ◽

Cited By ~ 1

Author(s):

Julius Pouchlý ◽

Antonín Živný ◽

Ján Biroš

Keyword(s):

Ternary Systems ◽

Heats Of Mixing

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Heats of mixing of butanone and chloroform with alkanes: Binary systems

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19780829 ◽

1978 ◽

Vol 43 (3) ◽

pp. 829-836 ◽

Cited By ~ 9

Author(s):

Ján Biroš ◽

Antonín Živný ◽

Julius Pouchlý

Keyword(s):

Binary Systems ◽

Heats Of Mixing

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Interpretation of heats of mixing of 1-butanol, 2-butanol and 2-methyl-2-propanol with cyclohexane in terms of some models of continuously associated solution

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19841334 ◽

1984 ◽

Vol 49 (6) ◽

pp. 1334-1341 ◽

Cited By ~ 3

Author(s):

František Veselý ◽

Vladimír Dohnal ◽

Miriam Valentová ◽

Jiří Pick

Keyword(s):

Temperature Dependence ◽

Interaction Parameters ◽

Heats Of Mixing ◽

Linear Association ◽

Two Systems ◽

Associated Solution

Three models of continuously associated solution complemented by an assumption of polynomial temperature dependence of corresponding interaction parameters were used for simultaneous description of the concentration and temperature dependence of heats of mixing of 1-butanol, 2-butanol and 2-methyl-2-propanol with cyclohexane. Very good results were reached for the first two systems where the Liebermann and Wilhelm model has proved to be the most suitable. With respect to the probable existence of cyclic associates in solutions of 2-methyl-2-propanol, none of the used models which assume only linear association satisfied to the extent required.

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