Complexes with ligands containing nitrile groups. Part II. Methyl cyanide complexes of some mono- and di-valent metal chlorides with tin tetrachloride

2010 ◽  
Vol 86 (10) ◽  
pp. 1103-1126 ◽  
Author(s):  
J. Reedijk ◽  
W. L. Groeneveld
Keyword(s):  
Metal Chlorides ◽  
Methyl Cyanide ◽  
Cyanide Complexes ◽  
Tin Tetrachloride

Preparation and characterization of some methyl cyanide complexes of Cu(I), Cu(II), and Zn(II) fluorosulfates

1970 ◽  
Vol 48 (1) ◽  
pp. 75-79 ◽  
Author(s):  
J. B. Milne
Keyword(s):  
Infrared Spectrum ◽  
Infrared Spectra ◽  
Strong Interaction ◽  
Strong Association ◽  
Conductivity Measurements ◽  
Methyl Cyanide ◽  
Cyanide Complexes

Tetrakis(methyl cyanide) complexes of Cu(I), Cu(II), and Zn(II) fluorosulfates have been prepared by reactions of anhydrous Cu(II) and Zn(II) fluorosulfates in methyl cyanide. The infrared spectra indicate a strong interaction between the fluorosulfate anion and the complex Cu(II) and Zn(II) cations. Conductivity measurements in methyl cyanide show strong association between the fluorosulfate anion and the dipositive cations. The Cu(I) compound is completely dissociated in methyl cyanide and, according to the infrared spectrum, shows no strong interaction with fluorosulfate anion.

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