The Abundances of Cobalt and Nickel in the Atmosphere of 78 Vir (A2p SrCrEu)

Cobalt and nickel abundances are rarely available for normal and Chemically Peculiar A stars because the strongest transitions of Co ii and Ni ii fall in the mid-UV. The abundances of cobalt and nickel are derived for 78 Vir using a mean mid-ultraviolet spectrum constructed by coadding 10 spectra collected with the Long Wave Prime and Long wavelength Redundant cameras over the 18 yr of the IUE mission. The strong transitions of Co ii at 2286.16 Å, 2307.86 Å, 2324.32 Å and 2580.33 Å and that of Ni ii et 2287.09 Å are present and more or less affected by blends. The least blended, λ 2286.16 Å, yields a mean overabundance of cobalt of 5 times the solar abundance, the Ni ii line at 2287.09 Å yields a 3 times solar overabundance. There is no convincing evidence that these lines varied in the spectra analyzed. The rotational period of 78 Vir estimated from its recent TESS lightcurve is 3.723 ± 0.055 days.

Kinetic and Metallography Study of the Oxidation at 1250 °C of {Co+Ni}-Based Superalloys Containing Ti to Form MC Carbides

Six conventionally cast chromium-rich titanium-containing alloys based on cobalt and nickel with various Co/Ni ratios were considered. They were tested in oxidation in air at 1250 °C for 70 h in a thermo-balance. The mass gain curves were exploited to specify different types of kinetic constants as well as several parameters characterizing the oxide spallation occurring during cooling. The obtained results show that, the higher the Ni content, the slower the mass gain and the better the quality of the protective external chromia scale. Secondly, no dependence of the oxide spallation characteristics on the Co content was clearly noted. Globally, the isothermal oxidation behavior becomes better when Ni is more and more present at the expense of Co. Titanium seems to be playing a particular role in the process of oxidation. It notably leads to the presence of an external thin TiO2 continuous scale beyond the chromia scale. The thermogravimetry records were numerically treated to determine the parabolic constant and the chromia volatilization constant. The values of these constants evidenced a double tendency: chromia growth acceleration and chromia volatilization slow-down. These trends are to be confirmed and further investigated.

Synthesis of composite materials on cobalt and nickel bases via centrifugal SHS-metallurgy

This paper discusses the synthesis regularities of new composite materials via combustion processes and their features of physicochemical transformations for task of a modern technology. In early studies, the authors showed the possibility of synthesizing composite materials via centrifugal SHS metallurgy, in which the combustion of thermite mixtures and the chemical transformations were studied. The compositions, structures and mechanical properties of the synthesized materials were also investigated

Obtaining and studying the properties of cobalt- and nickel-containing nanocomposites by thermolysis, using saturated carboxylates as precedors

Nickel (II) and cobalt (II) salts were synthesized with saturated monocarboxylic acids: butyric, valeric, nylon,enanthic, and caprylic. The obtained compounds were characterized by elemental analysis, IR spectroscopy,and differential scanning calorimetry. As a result of thermolysis of the synthesized carboxylates, nanocomposites were obtained, which were studied by scanning and transmission electron microscopy, elemental analysis, IR spectroscopy, energy dispersive X-ray spectroscopy, and X-ray phase analysis. The magnetic properties of the obtained nanocomposites have been studied.