Nitrogen fixation by reduced transition metal complexes: I. ESR measurements on a nitrogen-binding vanadium complex

2010 ◽  
Vol 90 (11) ◽  
pp. 1197-1206 ◽  
Author(s):  
T. P. M. Beelen ◽  
W. van Erk
Keyword(s):  
Nitrogen Fixation ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Vanadium Complex

Nitrogen Fixation by Transition Metal Complexes

Nature ◽  
1966 ◽  
Vol 209 (5029) ◽  
pp. 1236-1236 ◽  
Author(s):  
M. E. VOL'PIN ◽  
V. B. SHUR
Keyword(s):  
Nitrogen Fixation ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes

Development of Catalytic Conversion of Nitrogen Molecule into Ammonia Using Molybdenum Complexes under Ambient Reaction Conditions

2021 ◽  
Author(s):  
Yuya Ashida ◽  
Yoshiaki Nishibayashi
Keyword(s):  
Nitrogen Fixation ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Catalytic Conversion ◽  
Nitrogen Molecule ◽  
Reaction Conditions ◽  
Molybdenum Complexes

Nitrogen fixation using homogeneous transition metal complexes under mild reaction conditions is a challenging topic in the field of chemistry. Several successful examples of the catalytic conversion of nitrogen molecule...

Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments

2018 ◽  
Vol 2018 (12) ◽  
pp. 1337-1355 ◽  
Author(s):  
Nadja Stucke ◽  
Benedikt M. Flöser ◽  
Thomas Weyrich ◽  
Felix Tuczek
Keyword(s):  
Nitrogen Fixation ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Recent Developments

scholarly journals Nitrogen Fixation. I. Synthesis of Hydrazine from Molecular Nitrogen by Transition Metal Complexes.

1979 ◽  
Vol 33a ◽  
pp. 347-357 ◽  
Author(s):  
Börje Folkesson ◽  
Ragnar Larsson ◽  
Arne Kjekshus ◽  
Arne F. Andresen ◽  
Eberhard Hoyer ◽  
...  
Keyword(s):  
Nitrogen Fixation ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Nitrogen

scholarly journals Transition metal complexes with thiosemicarbazide-based ligands. Part 57: Synthesis, spectral and structural characterization of dioxovanadium(V) and dioxomolybdenum(VI) complexes with pyridoxal s-methylisothiosemicarbazone

2010 ◽  
Vol 75 (8) ◽  
pp. 1063-1074 ◽  
Author(s):  
Vukadin Leovac ◽  
Vladimir Divjakovic ◽  
Milan Joksovic ◽  
Ljiljana Jovanovic ◽  
Ljiljana Vojinovic-Jesic ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Elemental Analysis ◽  
Structural Characterization ◽  
Vanadium Complex ◽  
Molybdenum Complex ◽  
Octahedral Structure ◽  
X Ray

This work is concerned with the synthesis of neutral dioxovanadium(V) and dioxomolybdenum(VI) complexes with tridentate ONN pyridoxal S-methylisothiosemicarbazone (PLITSC) of the respective formulas [VO2(PLITSC-H)]?2H2O and [MoO2(PLITSC-2H)]. Structural X-ray analysis of the vanadium complex showed that it has an almost ideal square-pyramidal structure, while the molybdenum complex is supposed to have a polymeric octahedral structure. In addition to elemental analysis, both complexes were characterized by conductometric and magnetometric measurements, as well as by IR, UV-vis, 1H- and 13CNMR spectra.

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