Cyclopentanolates of Aluminum Hydride/Aluminum Chloride forming Aluminum-Oxygen-Hetero-Cages and Mixed Coordination Oligomers

2016 ◽  
Vol 642 (18) ◽  
pp. 973-978 ◽  
Author(s):  
Awadelkareem A. Ali ◽  
Volker Huch ◽  
Cenk Aktas ◽  
Michael Veith

1977 ◽  
Vol 42 (11) ◽  
pp. 1944-1947 ◽  
Author(s):  
Donald C. Kleinfelter ◽  
George Sanzero




1964 ◽  
Vol 42 (3) ◽  
pp. 572-578 ◽  
Author(s):  
George R. Pettit ◽  
Robert L. Smith

Successive conversion of N-bis(2-hydroxyethyl)-p-toluenesulphonamide (Ib) to respective dimethanesulphonate and difluoro derivatives (IIa, IIIa, and IIIc) was found to provide a convenient route to N-bis(2-fluoroethyl)amine. Reaction of N-bis(2-methanesulphonyl-oxyethyl)-p-toluenesulphonamide (IIIa) with limited quantities of potassium fluoride, in several pro tic solvents, was shown to yield N-(p-toluenesulphonyl)morpholine (IV). Utility of N-bis(2-fluoroethyl)amine as a precursor of fluoro-nitrogen mustards was illustrated by synthesis of two N-bis(2-fluoroethyl)benzylamines (IXb and Xa). Application of an aluminum chloride – lithium aluminum hydride reagent for hydrogenolysis of carbon–fluorine bonds was also suggested.



1972 ◽  
Vol 34 (8) ◽  
pp. 2439-2448 ◽  
Author(s):  
Masaki Yoshio ◽  
Nobuhiko Ishibashi ◽  
Hirohiko Waki ◽  
Tetsuro Seiyama




Sign in / Sign up

Export Citation Format

Share Document