The main contribution of this paper is the introduction of an intrinsic definition of the connective “fuzzy exclusive or” E (f-Xor E), based only on the properties of boundary conditions, commutativity and partial isotonicity-antitonicity on the the end-points of the unit interval U = [0,1], in a way that the classical definition of the boolean Xor is preserved. We show three classes of the f-Xor E that can be also obtained from the composition of fuzzy connectives, namely, triangular norms, triangular conorms and fuzzy negations. A discussion about extra properties satisfied by the f-Xor E is presented. Additionally, the paper introduces a class of fuzzy equivalences that generalizes the Fodor and Roubens's fuzzy equivalence, and four classes of fuzzy implications induced by the f-Xor E, discussing their main properties. The relationships between those classes of fuzzy implications and automorphisms are explored. The action of automorphisms on f-Xor E is analyzed.