Effects of CeO2 on Melting Temperature, Viscosity and Structure of Mold Fluxes for Casting Rare Earths Alloyed Steels

Author(s):  
Zeyun Cai ◽  
Bo Song ◽  
Longfei Li ◽  
Zhen Liu
2018 ◽  
Vol 206 ◽  
pp. 03005
Author(s):  
Bin Hou ◽  
Fengmei Liu ◽  
Hongqin Wang ◽  
Yupeng Zhang ◽  
Jianglong Yi ◽  
...  

In order to explore the effect of addition of mixed rare earths (MRE) on the wetting behavior and interfacial reaction between Sn-0.70Cu-0.05Ni solder and amorphous Fe84.3Si10.3B5.4 alloy, 0.25 wt.% percentage of the MRE, which are mainly elements La and Ce, were added into the solder. Results show it can refine the microstructure of the solder alloy, and there is limited change of melting temperature with the addition of MRE in the solder. The wettability of the solder on amorphous substrate is improved by adding 0.25 wt.% percentage of the MRE into Sn-0.70Cu-0.05Ni solder. Moreover, research results indicate that, with the increase of wetting temperature, the final equilibrium wetting angles of Sn-0.70Cu-0.05Ni and Sn-0.70Cu-0.05Ni-0.25MRE on amorphous substrate decrease gradually, indicating the better wettability at the higher wetting temperature. In addition, with the increase of temperature, the distribution of intermetallic compound (IMC) FeSn2 formed at the interface between the two solders and amorphous substrate is changed from discontinuous state to continuous state. The thickness of the interfacial IMC layer between solder and amorphous substrates reduced with the addition of MRE, indicating that the presence of 0.25 wt.% percentage of the MRE is effective in suppressing the growth of IMC layer.


Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 333 ◽  
Author(s):  
Zeyun Cai ◽  
Bo Song ◽  
Longfei Li ◽  
Zhen Liu ◽  
Xiaokang Cui

The CaO-Al2O3-based mold fluxes are proposed for the Ce-bearing heavy rail steel continuous casting because of the low reactivity. Effects of CeO2 on the melting temperature, the viscous property, and the crystallization behavior of the CaO-Al2O3-Li2O-B2O3 mold fluxes were studied using hemisphere melting point method, rotating cylinder method, and X-ray diffraction (XRD) in the present work. The microstructure of the mold fluxes was analyzed by Fourier-transform infrared spectroscopy (FTIR). The results revealed that the addition of CeO2 would increase the melting temperature, but decrease the viscosity at each temperature due to its influence on increasing the depolymerization of the mold fluxes at high temperature. The precipitation of CaO was restrained and CaCeAlO4 generated with increasing CeO2 content since the crystal phases were affected by the microstructure of the melts. The change of the crystalline phases in mold fluxes influences the break temperature and the viscosity of the mold fluxes below the break temperature. These results obtained can provide guidelines for designing new mold fluxes for casting rare earth alloy heavy rail steels.


1971 ◽  
Vol 32 (C1) ◽  
pp. C1-179-C1-185 ◽  
Author(s):  
S. CHIKAZUMI ◽  
K. TAJIMA ◽  
K. TOYAMA
Keyword(s):  

1979 ◽  
Vol 40 (C5) ◽  
pp. C5-17-C5-18
Author(s):  
M. de Jong ◽  
P. Touborg ◽  
J. Bijvoet

1988 ◽  
Vol 49 (C8) ◽  
pp. C8-511-C2-512 ◽  
Author(s):  
E. Gratz ◽  
E. Bauer ◽  
S. Pöllinger ◽  
H. Nowotny ◽  
A. T. Burkov ◽  
...  

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