The Quantum-to-Classical Transition of Primordial Cosmological Perturbations

Author(s):  
Nelson Pinto-Neto
1997 ◽  
Vol 497 (1-2) ◽  
pp. 479-508 ◽  
Author(s):  
J. Lesgourgues ◽  
David Polarski ◽  
A.A. Starobinsky

2021 ◽  
Vol 103 (12) ◽  
Author(s):  
Amin Rezaei Akbarieh ◽  
Sobhan Kazempour ◽  
Lijing Shao

1998 ◽  
Vol 57 (21) ◽  
pp. 13639-13654 ◽  
Author(s):  
D. A. Garanin ◽  
X. Martínez Hidalgo ◽  
E. M. Chudnovsky

1998 ◽  
Vol 63 (12) ◽  
pp. 1969-1976 ◽  
Author(s):  
Alvaro Domínguez ◽  
Rafael Jimenez ◽  
Pilar López-Cornejo ◽  
Pilar Pérez ◽  
Francisco Sánchez

Solvent effects, when the classical transition state theory (TST) holds, can be interpreted following the Brønsted equation. However, when calculating the activity coefficient of the transition state, γ# it is important to take into account that this coefficient is different from that of the precursor complex, γPC. The activity coefficient of the latter is, in fact, that calculated in classical treatments of salt and solvent effects. In this paper it is shown how the quotients γ#/γPC change when the reaction medium changes. Therefore, the conclusions taken on the basis of classical treatments may be erroneous.


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