Unusual Ligand Transformations and Rearrangements in Heterometallic Clusters

1995 ◽  
pp. 113-124
Author(s):  
Y. Chi ◽  
S-J. Chiang ◽  
C-J. Su
Keyword(s):  
Heterometallic Clusters

Syntheses, structures and properties of primarily nanosized homo/heterometallic palladium CO/PR 3 -ligated clusters

2010 ◽  
Vol 368 (1915) ◽  
pp. 1301-1332 ◽  
Author(s):  
Evgueni G. Mednikov ◽  
Lawrence F. Dahl
Keyword(s):  
Ground State ◽  
Closed Shell ◽  
Electron Configuration ◽  
Heterometallic Clusters ◽  
Structural Types ◽  
Metal Atoms ◽  
Shell Electron ◽  
Structures And Properties

Syntheses, properties and structures of nanosized palladium CO/PR 3 -ligated homo- and heterometallic clusters containing up to 165 metal atoms are the focus of this review. The work discussed is primarily that of the authors and their coworkers. We propose that the unparalleled variety of structural types and the distinctive reactivities of neutral Pd n (CO) x (PR 3 ) y clusters composed of zerovalent Pd atoms are a consequence of relatively weak Pd–L(ligand) and Pd(0)–Pd(0) interactions that result from the stable 5s 0 4d 10 closed-shell electron configuration of atomic Pd in its ground state.

Synthesis and structure of r—p-bridged trinuclear heterometallic clusters of manganese and chromium

1979 ◽  
Vol 178 (2) ◽  
pp. 319-324 ◽  
Author(s):  
Rajib Lal De ◽  
Joachim Von Seyerl ◽  
Gottfried Huttner
Keyword(s):  
Heterometallic Clusters

Wheel-type heterometallic ferromagnetic clusters: [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3)

2018 ◽  
Vol 47 (46) ◽  
pp. 16422-16428 ◽  
Author(s):  
Fumiya Kobayashi ◽  
Ryo Ohtani ◽  
Sotaro Kusumoto ◽  
Leonard F. Lindoy ◽  
Shinya Hayami ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Metal Ion ◽  
Heterometallic Clusters ◽  
Single Molecule Magnet ◽  
Ferromagnetic Properties ◽  
Behavior Based

Wheel-type heptanuclear heterometallic clusters display metal ion dependent ferromagnetic properties and express single molecule magnet behavior based on the magnetic anisotropy.

Heterometallische Cluster durch ligandunterstützte Metallfragmentkondensation / Heterometallic Clusters by Ligand Assisted Metal Fragment Condensation

1991 ◽  
Vol 46 (9) ◽  
pp. 1169-1176 ◽  
Author(s):  
Wolfgang Rohde ◽  
Gert Fendesak
Keyword(s):  
Double Bond ◽  
Chelate Complexes ◽  
Heterometallic Clusters ◽  
X Ray ◽  
X Ray Crystallography ◽  
Inert Solvent ◽  
Fragment Condensation ◽  
Olefinic Double Bond ◽  
High Yields ◽  
Iron Fragment

Dicobalt complexes of 3-vinylpropargylic alcohol derivatives react with biscyclooctenetricarbonyliron to give new chelate complexes of the iron tricarbonyl fragment with the olefinic double bond and the alcohol oxygen atom bound to the iron fragment. These compounds react upon heating in an inert solvent to give FeCo-alkynyl cluster complexes in high yields. One of these compounds has been structurally characterized by X-ray crystallography.

scholarly journals Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3 Mo3 Q8 (CN)6 ]n - (Q = S, Se)

2019 ◽  
Vol 2019 (22) ◽  
pp. 2685-2690
Author(s):  
Viktoria K. Muravieva ◽  
Yakov M. Gayfulin ◽  
Tatiana I. Lappi ◽  
Vincent Dorcet ◽  
Taisiya S. Sukhikh ◽  
...  
Keyword(s):  
Ligand Substitution ◽  
Heterometallic Clusters ◽  
Cyanide Ligand

Protein-Assisted Formation of Molybdenum Heterometallic Clusters: Evidence for the Formation of S2MoS2–M–S2MoS2Clusters with M = Fe, Co, Ni, Cu, or Cd within the Orange Protein

2017 ◽  
Vol 56 (4) ◽  
pp. 2210-2220 ◽  
Author(s):  
Biplab K. Maiti ◽  
Luisa B. Maia ◽  
Sofia R. Pauleta ◽  
Isabel Moura ◽  
José J. G. Moura
Keyword(s):  
Heterometallic Clusters ◽  
Orange Protein

Shedding light on the bonding situation of triangular and square heterometallic clusters: computational insight

2020 ◽  
Vol 44 (13) ◽  
pp. 5079-5087
Author(s):  
Daniel F. Coimbra ◽  
Alexandre O. Ortolan ◽  
Renato P. Orenha ◽  
Vanessa B. da Silva ◽  
Renato L. T. Parreira ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Heterometallic Clusters ◽  
Out Of Plane

DFT calculations reproduced the experimentally observed out-of-plane distortions in heterometallic clusters [MMoCp(CO)3]n (M = Cu+, Ag+ or Au+, n = 3 or 4); (Cp = η5-C5H5), while EDA analysis gives new insights into bonding situations.

Anion-Dependent Assembly of 3d–4f Heterometallic Clusters Ln5Cr2 and Ln8Cr4

2020 ◽  
Vol 59 (3) ◽  
pp. 1959-1966 ◽  
Author(s):  
Jia-Jia Yin ◽  
Cheng Chen ◽  
Gui-Lin Zhuang ◽  
Jun Zheng ◽  
Xiu-Ying Zheng ◽  
...  
Keyword(s):  
Heterometallic Clusters
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