Excess heat of mixing of binary mixtures of pyridine withn-alkanes at 313.15 K

1989 ◽  
Vol 35 (7) ◽  
pp. 2441-2446 ◽  
Author(s):  
H. Wilczura ◽  
T. Kasprzycka-Guttman
Keyword(s):  
Binary Mixtures ◽  
Heat Of Mixing ◽  
Excess Heat ◽  
Excess Heat Of Mixing

Excess heat of mixing of pyridine bases with toluene

1995 ◽  
Vol 44 (3) ◽  
pp. 563-570 ◽  
Author(s):  
H. Wilczura ◽  
T. Kasprzycka-Guttman ◽  
A. Myslinski
Keyword(s):  
Heat Of Mixing ◽  
Excess Heat ◽  
Pyridine Bases ◽  
Excess Heat Of Mixing

Excess heat of mixing of 1-propanol or 2-propanol with benzene, toluene, o-, m- and p-xylenes at 298.15 K

1996 ◽  
Vol 276 ◽  
pp. 271-285 ◽  
Author(s):  
K.C Singh ◽  
K.C Kalra ◽  
Sanjeev Maken ◽  
Vibha Gupta
Keyword(s):  
Heat Of Mixing ◽  
Excess Heat ◽  
Benzene Toluene ◽  
Excess Heat Of Mixing

Excess heat of mixing of α-picoline withn-alkanes

1992 ◽  
Vol 38 (6) ◽  
pp. 1357-1364 ◽  
Author(s):  
T. Kasprzycka-Guttman ◽  
H. Wilczura ◽  
A. Myslinski
Keyword(s):  
Heat Of Mixing ◽  
Excess Heat ◽  
Excess Heat Of Mixing

Excess heat of mixing of 1-propanol or 2-propanol with benzene, toluene, o-, m- and p-xylenes at 298.15 K

1996 ◽  
Vol 275 (1) ◽  
pp. 51-65 ◽  
Author(s):  
K.C. Singh ◽  
K.C. Kalra ◽  
Sanjeev Maken ◽  
Vibha Gupta
Keyword(s):  
Heat Of Mixing ◽  
Excess Heat ◽  
Benzene Toluene ◽  
Excess Heat Of Mixing

The Heat of Mixing for Binary Mixtures of Triethylamine with Alcohols

1961 ◽  
Vol 14 (4) ◽  
pp. 520 ◽  
Author(s):  
TJV Findlay
Keyword(s):  
Binary Mixtures ◽  
Vapour Pressure ◽  
Alcohol Molecule ◽  
Heat Of Mixing ◽  
Pressure Data ◽  
Calorimetric Measurements

Calorimetric measurements of the heat of mixing have been made at 25 �C and 40 �C for binary mixtures of triethylamine with methanol, and at 25 �C and 45 �C for binary mixtures of triethylamine with ethanol, n-propanol, and n-butanol. It is found that the heat of mixing for these systems becomes slightly less negative as the temperature is increased. However, apart from methanol, the size of the alcohol molecule has little effect on the heat of mixing. The results obtained are compared with those calculated from vapour pressure data in an earlier paper.

Simultaneous correlation of vapour-liquid equilibrium and heats of mixing and prediction of excess heat capacities. The systems benzene-n-alcohols and cyclohexane-n-alcohols

1979 ◽  
Vol 44 (3) ◽  
pp. 808-822 ◽  
Author(s):  
Vladimír Dohnal ◽  
Jaroslav Vinš ◽  
Robert Holub
Keyword(s):  
Experimental Data ◽  
Binary Systems ◽  
Heat Capacities ◽  
Heat Of Mixing ◽  
Data Sets ◽  
Wilson Equation ◽  
Excess Heat ◽  
Excess Heat Capacities ◽  
Heats Of Mixing ◽  
Quadratic Temperature

The Wilson, the enthalpic Wilson and the Orye equations were used for the simultaneous correlation of extensive data sets on VLE and heats of mixing of eight binary systems hydrocarbon-n-alcohol, viz. benzene-methanol, -ethanol, -n-propanol, -n-butanol, cyclohexane-ethanol, -n-propanol, -n-butanol and n-heptane-ethanol. The expected quadratic temperature dependence of parameters of these equations makes a good simultaneous description possible of excess free enthalpy and heat of mixing as a function of temperature. The Wilson equation gives demonstrably the best description of the experimental data. All the equations were as well used to predict excess heat capacities for the systems listed and the confidence intervals were estimated for the predicted results. The comparison with experimental data for four of these systems shows that the predicted excess heat capacities are in general in good agreement with the experiment; however, the Wilson equation yielded again the best results.

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